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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 854-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Following secondary recovery processes in conventional light oil reservoirs, more than half the original oil in place may remain trapped as a discontinuous phase. During the previous recovery processes these oil ganglia have been pinched off by capillary forces and remain immobile while the continuous phase which surrounds them is able to flow freely. Furthermore if a portion of this oil is mobilized in a tertiary recovery process the conditions required to apply Darcy's equation to the flow of either phase are violated. These are also problems which are encountered during in-situ recovery techniques in tar sands where the mobilization of the heavy oil occurs as a discontinuous phase. In this paper the relevant flow equations are derived. Also a parameter is deduced which directly determines the criterion for mobilization.
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 14 (1993), S. 503-514 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Design of molding tools and molding cycles for sheet molding compounds (SMC) is often expensive and time consuming. Computer simulation of the compression molding process is a desirable approach for reducing actual experimental runs. The focus of this work is to develop a computer model that can simulate the most important features of SMC compression molding, including material flow, heat transfer, and curing. A control volume/finite element approach was used to obtain the pressure and velocity fields and to compute the flow progression during compression mold filling. The energy equation and a kinetic model were solved simultaneously for the temperature and conversion profiles differential scanning calorimetry (DSC) was used to experimentally measure the polymer zation kinetics. A rheometrics dynamic analyzer (RDA) was used to measure the rheological changes of the compound. A series of molding experiments was conducted to record the flow front location and material temperature. The results were compared to simulated flow front and temperature profiles.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2339-2345 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The state of p-phenylphenol molecules in dioxane/water mixture, a commonly used reaction system for enzymatic polymerization of phenols and aromatic amines, was investigated by difference UV absorption spectroscopy and Fourier transform (FT) Raman spectroscopy. The aggregate of p-phenylphenols is found on the basis of the exciton peaks observed in difference UV absorption spectra. FT Raman spectroscopy demonstrates further that p-phenylphenol molecules aggregate together in “face to face” fashion. A simplified model is proposed for aggregation of p-phenylphenol molecules in dioxane/water mixture, which can elucidate the variation of the molecular weight of poly (p-phenylphenol) coupled in the reaction system. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 2503-2509 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(2,6-dimethyl-1,4-phenylene oxide) has been crosslinked in the presence of large poly(dimethylsiloxane) cyclics (92 repeating units). Approximately 26% by weight of the cyclics were threaded and permanently captured by the polymer network forming a topological isomeric structure referred to as a polymeric catenane. Nonentrapped cyclics were extracted with chloroform. Chemical analyses and micrographs showed evidence for crosslinking and cyclic entrapment, while physical testing demonstrated distinct differences in physical properties such as the glass transition temperature, ultimate mechanical properties, and dynamic viscoelastic response between the crosslinked control samples, and those containing cyclic poly(dimethylsiloxane).
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 24 (1986), S. 229-232 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 1667-1673 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The design of spiroorthocarbonate monomers (SOCs) and related structures is discussed with the aim of maximizing monomer polymerizability in the absence of undesirable byproducts. The successful syntheses of N,S-analogs of aryl- and alkaryl-SOCs are reported; these are monomers of structure where P and Q are —O— and —OC(CH3)2-, mp 156-158°C; and P and Q are —OCH2— and —OCH2—, mp 148-150°C. As is indicated by infrared spectra, the polymerization of both monomers is initiated by boron trifluoride etherate. © 1993 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2039-2047 
    ISSN: 0887-624X
    Keywords: liquid crystal ; cyclic siloxane ; hydrosilation ; cholesterol ; biphenyl ; phase behavior ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of 24 cyclic siloxane-based liquid crystalline compounds was synthesized using conventional hydrosilation chemistry. Variables examined included ring size, spacer group length, and type and composition of pendant mesogeric groups. Both pentamethylhydro- and tetramethylhydrosiloxane rings were reacted with mesogens based on cholesterol, biphenyl, or equimolar mixtures of both. Four different length spacer groups containing terminal vinyl groups were used to attach the mesogens to the cyclic siloxane core. The thermotropic liquid crystalline phase behavior was studied using differential scanning calorimetry (DSC) and polarized optical microscopy (POM). A lengthening of spacer groups resulted in lower crystallization temperatures for the biphenyl-based compounds and lower glass transition temperatures for the cholesterol- and mixed mesogen-based compounds. The tetramethyl ring derivatives exhibited higher glass transition or crystallization temperatures than their pentamethyl counterparts. Biphenyl-based compounds exhibited low temperature crystalline phases while the cholesterol-based compounds exhibited low temperature glassy phases. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 588-588 
    ISSN: 0935-6304
    Keywords: Capillary columns ; End sealing ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 9
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Fragment ions from underivatized N-linked oligosaccharides ionized by matrix-assisted laser desorption/ionization mass spectrometry were obtained by spontaneous fragmentation on a magnetic sector mass spectrometer, by post-source decay (PSD) on a reflectron time-of-flight (TOF) instrument and by collision-induced dissociation on a magnetic sector instrument fitted with an orthogonal-TOF analyser. Spontaneous fragmentation on the magnetic sector instrument produced ions mainly by glycosidic cleavage together with two abundant ions formed by cross-ring cleavage of the reducing-terminal residue. The PSD spectra were similar, the majority of ions being formed by glycosidic cleavage. Internal fragment ions were abundant. High-energy collision-induced dissociation spectra, recorded with the orthogonal-TOF analyser, differed considerably from the other types of spectra, particularly in the appearance of major fragment ions produced by cross-ring cleavages of most of the constituent monosaccharide residues. These ions allowed much sequence and branching information to be obtained from the oligosaccharide.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1977), S. 159-171 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chemical ionization mass spectrometry is used at low resolution to determine the sequences of permethylated acetyl peptides. The method has been tested with 45 peptides, between 2 and 5 residues long, including examples of all of the common amino acids except cysteine and N-terminal asparagine. The isobutane chemical ionization spectra contain three principal types of N-terminal sequence ion and one type of C-terminal sequence ion. The redundant information available from these four types of sequence ion increases the reliability of the sequence determination. In prospect, isobutane chemical ionization mass spectrometry seems to be a useful technique for peptide sequence determination, and may have advantages in some cases.
    Additional Material: 2 Ill.
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