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  • Chemistry  (239)
  • 2005-2009  (1)
  • 1950-1954  (151)
  • 1945-1949  (87)
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  • 1
    Publication Date: 2020-12-21
    Description: This paper introduces the three-dimensional Hamburg Model of the Neutral and Ionized Atmosphere (HAMMONIA), which treats atmospheric dynamics, radiation, and chemistry interactively for the height range from the earth’s surface to the thermosphere (approximately 250 km). It is based on the latest version of the ECHAM atmospheric general circulation model of the Max Planck Institute for Meteorology in Hamburg, Germany, which is extended to include important radiative and dynamical processes of the upper atmosphere and is coupled to a chemistry module containing 48 compounds. The model is applied to study the effects of natural and anthropogenic climate forcing on the atmosphere, represented, on the one hand, by the 11-yr solar cycle and, on the other hand, by a doubling of the present-day concentration of carbon dioxide. The numerical experiments are analyzed with the focus on the effects on temperature and chemical composition in the mesopause region. Results include a temperature response to the solar cycle by 2 to 10 K in the mesopause region with the largest values occurring slightly above the summer mesopause. Ozone in the secondary maximum increases by up to 20% for solar maximum conditions. Changes in winds are in general small. In the case of a doubling of carbon dioxide the simulation indicates a cooling of the atmosphere everywhere above the tropopause but by the smallest values around the mesopause. It is shown that the temperature response up to the mesopause is strongly influenced by changes in dynamics. During Northern Hemisphere summer, dynamical processes alone would lead to an almost global warming of up to 3 K in the uppermost mesosphere.
    Description: Published
    Description: 3903-3931
    Description: reserved
    Keywords: Sensitivity ; Chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 25 (1953), S. 672-676 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Während die Vorgänge bei der Verdampfung unter Atmosphärendruck vor allem durch Jacob und Mitarbeite weitgehend geklärt sind, besteht über die Verdampfung im Hochvakuum noch keine einheitliche Vorstellung. In jüngerer Zeit veröffentlichte Untersuchungen von K. C. D. Hickman und D. J. Trevoy1 geben einen Einblick in die Hochvakuum-Verdampfung und Molekular-Destillation, über welche nachfolgend berichtet wird.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 1 (1946), S. 535-539 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the rolling of Plastic sheet the viscous work gives rise to heating of the plastic sheet. The maximum temperature reached in the interior of the sheet during shearing is of the interest, both in the theoretical calculation of roll pressure, and from the point of view of possible thermal decomposition effects. A calculation is given for a simple, some-what artificial, model, which leads to an upper value for this maximum temperature if a measurement of the average temperature of the emergent sheet is given. The model taken is that of an infinite sheet, of thickness 2δ, in which heat is continuously liberated at the rate of 4ηφ2 cal. cc. -1 sec. -1, where φ is the relevant value of the rate of compression (assumed constant across the sheet). The curve giving the temperature distribution across the sheet is calculated numerically for two cases; it is relatively flat, as would be expected on physical grounds, since the viscosity, η, decreases as the temperature rises. It is concluded that these thermal effects may be neglected in the calculation of roll pressure in Part 1.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 1 (1946), S. 529-534 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An elementary theory is given for the rolling of polymeric materials, for the case in which the deformation is largely an irreversible flow of the viscous type. The theory treats the rolling process as the homogeneous deformation of volume elements over the arc of contact and neglects frictional forces that may exist at the roll surface. A numerical example is given of the calculation of roll pressure, which agrees with available data to a factor of two or better. A more complete test will require parallel measurements of viscosity and roll pressure on the same material.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 449-449 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 3 (1948), S. 345-349 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The surface tension of polyoxyethylene glycol in water leads to a value for the area per molecule which shows that the polymer molecules lie approximately flat in the surface. Molecular weight determinations by end-group analysis and freezing-point depression are compared with values of the intrinsic viscosity and limiting area per molecule.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 306-313 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Methods for the preparation of fiber-forming polymeric amides from polymethylene diamines and polymethylene dicarboxylic acids, and the stabilization of these polymers against viscosity changes, have been described. The variation in physical properties, particularly melting points, of the polymeric amides with increasing chain length of the components has been discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 352-352 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 11 (1953), S. 225-231 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: For a particular sample of polystyrene, different osmometric estimates of Mn have been reported. The possibility that the difference is due, in the one case, to permeation of the membrane by low molecular weight polymer has been carefully considered. It is shown that this can not be the explanation. The difference is in some way associated with chemical differences in the membranes used. Apart from these considerations of error, the significance of the number-average molecular weights of the unfractionated polymers of commerce is shown to be more acutely dependent upon the detail of the low molecular weight end of the distribution than may be realized. The present calculations are based upon a realistic estimate of the low molecular weight polymer content of commercial polymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Methods for the preparation of fiber-forming polymeric amides from ω-amino acids and The variation in melting points of the polymeric their amide-forming derivatives are described. The variation in melting points of the polymeric amides with increasing chain length of the recurring unit is discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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