ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The chemical engineer frequently has to correlate kinetic data for heterogeneous reactions simply and accurately in order to make useful predictions of reaction rates over a range of conditions. The Langmuir-Hinshelwood approach, which is frequently used for this purpose, does not have the theoretical validity commonly attributed to it, and its use leads to unnecessary mathematical complexity. A simpler method of analysis is suggested which is based on power dependencies of the rate on concetrations, the powers being restricted to integral of half-integral values. The data for several reactions are shown to be adquately correlated by the suggested procedure, which is simple and convenient.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690020112
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