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  • Chemistry  (31)
  • 1980-1984  (26)
  • 1975-1979  (5)
  • 1
    Electronic Resource
    Electronic Resource
    A cation exchange resin from poly(N-vinyl carbazole) (1978)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 72 (1978), S. 57-66 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(N-vinylcarbazol) wurde mit verschiedenen Reagenzien sulfoniert und die Ionenaustauschkapazität der erhaltenen Harze bestimmt. Eine maximale Kapazität von 4,5 meq · g-1 des trockenen Harzes wurde durch 10stündige Reaktion mit 98,8proz. H2SO4 bei 30°C erhalten. Die pH-Titrationskurven lassen einen starken monofunktionellen Kationenaustauscher mit einem pK-Wert von 2,2 erkennen. Das Harz zeigt eine mäßige Austauschgeschwindigkeit mit NaCl und ist bis zu 250°C thermisch stabil.
    Notes: Poly(N-vinyl carbazole) was sulfonated with different sulfonating agents and ion exchange capacities of the resins produced were evaluated. A maximum capacity of 4.5 meq · g-1 of dry resin was realized when sulfonation was done with 98.8% H2SO4 at 30°C for 10 h. The pH titration curves reveal the nature of a strong monofunctional cation exchanger with a pK value of 2.2. The resin exhibits a moderate rate of exchange with NaCl and is thermally stable up to ca. 250°C.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1978.050720105
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  • 2
    Electronic Resource
    Electronic Resource
    A cation exchange resin based on the condensation product of poly(iso-butyl vinyl ether) and furfural (1978)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 73 (1978), S. 53-61 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Kationenaustauscher wurde durch Kondensation von Polyisobutylvinyläther und Furfural hergestellt. Als Katalysator diente konzentrierte Schwefelsäure. Der Austauscher wurde durch Messen der Austauschkapazität, durch Untersuchen seiner thermischen Belastbarkeit und durch Bestimmen seines Verhaltens bei der pH-Titration charakterisiert. Es scheint sich um einen Austauscher mit schwachen Säregruppen zu handlen, die wohl als —COOH-Gruppen vorliegen und durch Oxidation aus den Furfuralgruppen entstanden sein dürften.
    Notes: A cation exchange resin was synthesized from the condensation product of poly(iso-butyl vinyl ether) and furfural by treating it with concentration sulphuric acid. The resin produced was characterized by measuring its total and salt splitting capacities, and by studying its thermal characteristics and behaviour to pH metric titration. The latter suggests the resin to be a weak one possibly containing —COOH groups, which result from the oxidation of the furfural aldehyde group by sulphuric acid.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1978.050730104
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  • 3
    Electronic Resource
    Electronic Resource
    Studies on carbazole based polyarylates (1981)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 97 (1981), S. 79-90 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde ein neues Polyarylat aus Carbazol und Resorcinol nach der Methode der Lösungskondensation bei niedriger Temperatur unter Verwendung von Pyridin als Katalysator hergestellt. Das Polymere wurde im Hinblick auf seine Struktur, thermische Stabilität und sein dielektrisches Verhalten charakterisiert. Der Einfluß des Diphenolenteils auf die thermischen und dielektrischen Eigenschaften dieses Polyarylats und anderer auf Carbazolbasis wurde untersucht.
    Notes: A novel polyarylate has been synthesized from carbazole and resorcinol by low temperature solution condensation method using as an acceptor-catalytic reagent pyridine. It has been characterized in respect of its structure, thermal stability and dielectric behaviour. The influence of the diphenol moiety on the thermal and the dielectric properties of this polyarylate and the others based on carbazole has been studied.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1981.050970107
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  • 4
    Electronic Resource
    Electronic Resource
    Chemical modification of polystyrene, III. Electrophilic substitution of polystyrene with aromatic anhydrides (1983)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 113 (1983), S. 11-19 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Polystyrol wurde durch Friedel-Crafts-Acylierung mit Trimellithsäureanhydrid in Gegenwart von wasserfreiem Aluminiumchlorid als Katalysator chemisch modifiziert. Das Produkt wurde hinsichtlich seiner Struktur und physikalisch-chemischen Eigenschaften durch Messung der Gesamtkapazität, der thermischen Stabilität und des Titrationsverhaltens charakterisiert. Die thermischen Kenngrößen des mit Trimellithsäureanhydrid modifizierten Polystyrols wurden im Hinblick auf ihre strukturellen Eigenheiten mit denen des mit Phthalsäureanhydrid und mit Pyromellithsäuredianhydrid modifizierten Polystyrols verglichen.
    Notes: Polystyrene has been chemically modified by Friedel-Crafts acylation reaction with trimellitic anhydride in the presence of anhydrous aluminium chloride as catalyst. The product has been characterized in respect of its structure and physicochemical properties by measuring its total capacity, thermal stability and the behaviour to pH metric titration. The thermal characteristics of the trimellitic anhydride modified polystyrene have been compared with the same for phthalic anhydride and pyromellitic dianhydride modified polystyrene in the light of their structural characteristics.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1983.051130102
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  • 5
    Electronic Resource
    Electronic Resource
    Rotating element model for low density polyethylene (1984)
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 5 (1984), S. 441-446 
    Details
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/marc.1984.030050804
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  • 6
    Electronic Resource
    Electronic Resource
    Composite model for the mechanical and optical properties of a semicrystalline polymer, polyoxymethylene (1984)
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 5 (1984), S. 295-299 
    Details
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/marc.1984.030050509
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  • 7
    Electronic Resource
    Electronic Resource
    Chemical modification of poly(N-vinylcarbazole). II. Some properties of poly(N-vinylcarbazole-3,6-diphthalimide) (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 20 (1982), S. 333-339 
    Details
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.130200608
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  • 8
    Electronic Resource
    Electronic Resource
    Chemical modification of poly(N-vinylcarbazole): Synthesis of poly(N-vinylcarbazole-3,6-diphthalimide) of improved thermal stability (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 19 (1981), S. 235-238 
    Details
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.130190503
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  • 9
    Electronic Resource
    Electronic Resource
    Phthalic anhydride-based cation exchange resin from N-vinylcarbazole (1980)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 511-518 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A condensation product based on phthalic anhydride and N-vinylcarbazole has been prepared and processed into a sulfonic acid cation exchange resin. The resin produced has been characterized by measuring its total and salt splitting capacities and by studying its thermal characteristics, rate of exchange, and behavior to pH metric titration.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1980.070250316
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  • 10
    Electronic Resource
    Electronic Resource
    Cation exchange resin from sulfonated N-vinylcarbazole and divinylbenzene copolymer (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 1719-1725 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A copolymer of N-vinylcarbazole and divinylbenzene has been sulfonated to yield a cation exchange resin of improved thermal properties compared to other vinylcarbazole-based resins. The resin has been characterized by measuring its total and salt-spliting capacities, pH metric titration, and thermal stability characteristics.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260526
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