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  • 1
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Koordinationspolymere von 5,8-Dihydroxy-1,4-naphthochinon mit Fe(III), Co(II) and Ni(II) wurden hergestellt und durch Elementaranalyse, DSC, IR-Spektroskopie und Messung der magnetischen Momente charakterisiert. Aus den DSC-Daten wurden die Reaktionsordnungen und die Aktivierungsenergien des thermischen Abbaus der Polymeren berechnet. Die elektrischen Eigenschaften wie Dielektrizitätskonstante und Wechselstromleitfähigkeit wurden gemessen. Aus Röntgen-Pulverdiagrammen wurden die Elementarzellenparameter berechnet und die Kristallsymmetrie bestimmt.
    Notes: Coordination polymers of Fe(III), Co(II) and Ni(II) with 5,8-dihydroxy-1,4-naphthoquinone have been synthesized and characterized by elemental analysis, IR and magnetic moment studies. From DSC data, the order of the decomposition reaction and the activation energy for the decomposition of the different polymers have been evaluated. Electrical properties like the dielectric constant and the dc conductivity of the polymers have been measured. From x-ray powder diffractograms cell parameters were calculated, the pattern indexed, and the symmetry determined.
    Additional Material: 5 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electrophoresis 15 (1994), S. 907-910 
    ISSN: 0173-0835
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: A method is described for the direct detection of lectins, agglutinating erythrocytes, on nitrocellulose membranes after Western blotting, thus avoiding protein extraction from specific bands in the gel, followed by agglutination assays. The methodology essentially involves exposing the lectin band on a nitrocellulose strip to trypsinized rabbit erythrocytes (2%, in 0.15 M NaCl) for 30 min at 37°C and then carefully transferring the membrane to saline (4°C) for a few gentle washes and then fixing it in a solution (0.2% glutaraldehyde in 0.15 M NaCl) for 30 min. Later, the membrane is gently washed several times in 0.15 M NaCl containing 10 mM β-alanine. The lectin band is visualized as a red agglutinated patch. The method is specific for lectins that can agglutinate red blood cells and virtually has no cross reactivity with the various nonlectin proteins tested. Binding of erythrocytes to the lectin band on the nitrocellulose strip can be prevented by specific competing sugars. The method can be applied to screen for the presence of lectins in natural materials and to monitor lectin fractions during purification.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 42 (1991), S. 379-383 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Mechanismus der Ladungsspeicherung in Poly(acrylamid)-Filmen wurde mit der Methode der thermisch stimulierten Depolarisationsströme (TSDC) untersucht. Die TSDC wurden in Abhängigkeit von der Feldstärke, der Temperatur und der Dauer der Polarisation bei verschiedenen Aufheizgeschwindigkeiten gemessen. Bei niedrigen Polarisationstemperaturen wurde in den TSDC-Spektren nur ein Peak gefunden, bei höheren Polarisationstemperaturen traten zwei Peaks auf. Der erste Peak wurde der Dipolorientierung, der zweite der Raumladungspolarisation zugeordnet.
    Notes: The charge storage mechanism in poly(acrylamide) films was studied by means of the technique of thermally stimulated depolarization currents (TSDC). The TSDC were measured as a function of field strength, temperature and time of polarization in dependence on the heating rate. One peak was observed on the TSDC spectra at low polarizing temperatures, while two peaks occurred for higher polarizing temperatures. The first peak was attributed to dipole orientation and the second one to space charge polarization.
    Additional Material: 10 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 42 (1991), S. 465-469 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die stationäre elektrische Leitung in aus der Lösung erhaltenen Poly(acrylamid)-Filmen wurde im Temperaturbereich von 303 bis 450 K bei unterschiedlichen Feldstärken untersucht. Es wurde festgestellt, daß die Richardson-Schottky- und Poole-Frenkel-Mechanismen gleichzeitig auftreten. In mit Eosin bzw. Rhodamin B dotierten Filmen wurde die elektrische Leitung der Bildung von Charge-Transfer-Komplexen zugeschrieben.
    Notes: The steady state electrical conduction in solution grown poly(acrylamide) films was investigated in the temperature range 303 to 450 K at different field strengths. It was found that the Richardson-Schottky and Poole-Frenkel mechanisms operate simultaneously. In films doped with cosin and rhodamine B, respectively, the electrical conduction was attributed to the formation of charge transfer complexes.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 43 (1992), S. 68-71 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(vinylalkohol)-Filme wurden bei unterschiedlichen elektrischen Feldstärken und Temperaturen polarisiert. Die Peaktemperatur der TSDC-Spektren verschob sich mit steigender Polungsfeldstärke und Polungstemperatur zu höheren Werten. Die Aktivierungsenergien und die Relaxationsparameter des Prozesses wurden ermittelt. Auf Grund der Ergebnisse wurde der Ursprung der TSDC der Raumladungspolarisation mit einem geringen von der Dipolorientierung herrührenden Beitrag zugeordnet.
    Notes: Poly(vinyl alcohol) films were polarized at different electrical field strengths and temperatures. The peak temperature of the TSDC spectra shifted to higher values with increasing polarizing field strength and polarizing temperature. The activation energies and relaxation parameters of the process were evaluated. Based on the results, the origin of TSDC was attributed to space charge polarization with some contribution of dipole orientation.
    Additional Material: 7 Ill.
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  • 6
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Films aus Mischungen von Poly(vinylalkohol) und Poly(vinylpyrrolidon) wurden aus Lösungen der Homopolymere hergestellt. Die stationäre elektrische Leitung wurde im Temperaturbereich 309 K bis 450 K bei Feldstärken von 0,75 bis 46,5 · 106 V/m unter Verwendung unterschiedlichen Elektrodenmaterials untersucht. Der Ladungstransport wird mit der Injektion von Ladungsträgern aus dem Elektrodenmaterial in das Dielektrikum nach einem Richardson Schottky-Mechanismus und nachfolgendem Einfangen und Freisetzung nach dem Poole-Frenkel-Mechanismus erklärt.
    Notes: Polyblend films of poly(vinyl alcohol) and poly(vinyl pyrrolidone) were prepared from solutions of the homopolymers. The steady-state electrical conduction was studied in the temperature range from 309 K to 450 K at the field strength of 0.75 to 46.5 · 106 V/m using different electrode materials. The charge transport is attributed to the injection of charge carriers from the electrode materials into the dielectric according to the Richardson-Schottky mechanism and their subsequent trapping and release according to the Poole-Frenkel mechanism.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 935-945 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Oxoalkyl acrylates of long-chain 7-oxo alcohols were synthesized as intermediate monomers for the preparation of poly[n-alkyl (oxy) -n-hexyl acrylates] for the first time. These polymers have wide applications as fluidity improvers (pour point depressants) for petroleum crude oils. Characterization of all the intermediate monomers was done by IR, 1H-NMR, and MS, and that of polymers by IR, 1H-NMR, and GPC. These polymers were systematically investigated for their efficacy as pour point depressants on three types of high waxy Bombay High (Indian) crudes. In addition to establishing the pour points, relevant rheological parameters of the untreated and the additive-treated crude oils were determined in the laboratory with a rotational viscometer. Results of the crude oils that were pre- and posttreated with these new polymers have shown enhanced activity of flow properties as compared to the crudes that were treated with poly(n-alkyl acrylate) flow improver.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 21 (1992), S. 239-243 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The dependence of the Kβ/Kα ratio on the chemical constitution of the x-ray emitting atom of 3d-shell elements. V, Cr, Mn and Fe, was studied employing a high-resolution Si(Li) detector. A maximum deviation of 9% in the Kβ/Kα ratio for the elements V and Mn is found when compared with their respective compounds. The experimental results are found to be consistent with the theoretical values due to Brunner's model.
    Additional Material: 2 Ill.
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  • 9
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A systematic study of Lα/Lβ and Lα/Lγ x-ray intensity ratios was undertaken by measuring the characteristic x-ray intensities in 23 elements over the range Z = 55-80, using a 30 mCi 238Pu source of excitation and a high-resolution Si(Li) detector system coupled to a computer-controlled multi-channel analyser. The theoretical predictions due to Scofield were computed for the present energy (weighted average) of 15.28 keV excitation and compared with the experimental values. The experimental values of Lα/Lβ and Lα/Lγ versus Z were fitted to a fourth-degree polynomial, and most probable values of Lα/Lβ and Lα/Lγ at each Z were also determined using this fit.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 811-820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A framework is developed to describe kinetics and column dynamics of ad(de)sorption from bulk liquid mixtures using surface excess as the variable to quantify the extent of adsorption. It is found that the transient rate of change of surface excess with time from a multicomponent liquid mixture can be expressed in terms of a surface excess linear-driving-force model. A local-equilibrium model can be developed to describe the column dynamics of ad(de)sorption from liquid mixtures. Both self-sharpening and proportionate pattern mass-transfer zones can be formed depending on the shape of the surface-excess isotherm and the selectivity of adsorption. Analysis of column dynamics for liquid mixture adsorption can be carried out analogous to that for adsorption from gas mixtures, when a constant pattern mass-transfer zone is formed. The length of the mass-transfer zone and the composition-time column effluent profile can also be derived analytically for such a case. Experimental kinetics and column dynamics data for ad(de)sorption of ethanol-water mixtures on a large-pore activated carbon are analyzed using these models.
    Additional Material: 7 Ill.
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