ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Polysulfonyl Amines. XX. (1/1) Molecular Adducts of Di(organosulfonyl) Amines with Triphenylphosphine Oxide. X-Ray Structure Determination of Dimesylamine-Triphenylphosphine Oxide (1/1)From equimolar solutions of the respective components in organic solvents, crystalline addition compounds of composition (RSO2)2NH · OP(C6H5)3 are obtained, where R = CH3, C6H5, 4-X—C6H4 (X = CH3, F, Cl, Br, NO2) or 3-NO2—C6H4. (CH3SO2)2NH · OP(C6H5)3 crystallizes in the monoclinic space group P21/n. A short NH⃛O hydrogen bond [N⃛O 266.1(5) pm] connects the dimesylamine molecule with the triphenylphosphine oxide molecule.
Notes:
Aus äquimolaren Lösungen der jeweiligen Komponenten in organischen Lösemitteln werden kristalline Addukte der Zusammensetzung (RSO2)2NH · OP(C6H5)3 mit R = CH3, C6H5, 4-X—C6H4 (X = CH3, F, Cl, Br, NO2) sowie 3-NO2—C6H4 erhalten. (CH3SO2)2NH · OP(C6H5)3 kristallisiert in der monoklinen Raumgruppe P21/n. Eine kurze Wasserstoffbrücke des Typs NH⃛O [N⃛O 266,1(5) pm] verknüpft das Dimesylamin- mit dem Triphenylphosphinoxid-Molekül.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19905890118
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