ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 245-249 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Spectroscopic Investigations on the Acidity of O,O′-Dithiophosphoric Acid Esters in Nonpolar Aprotic Solvents
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As masked 1,3-dicarbonyl compounds, 1,1-dioxo-2H-1,2-thiazine-4-carbaldehydes (2a-e, 7) undergo ring transformations with nucleophilic hydrazines to produce 4-[1-methyl-2-(arylsulfamoyl)vinyl]pyrazoles (9a-i). For 9h, an X-ray structural analysis is reported. With less nucleophilic semicarbazide and p-nitrophenylhydrazine the hydrazones (11a, b) were isolated. The carbaldehydes 2a-e, 7 and 8a, b were synthesized by formylation of the 1,1-dioxo-2H-1,2-thiazines 1a-e, 5 and 6a, b with dichloromethyl methyl ether/TiCl4. In the case of 1a-e mixtures of 4- and 6-carbaldehydes (2a-e/3a-e) were obtained, which, however, could be used for the synthesis of pyrazoles.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 647-654 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Structure of Basic Zinc-O,O′-2-ethylhexyldithiophosphates in Apolar Aprotic SolventsA sample of technically used Zinc-O,O′-2-ethylhexyldithiophosphate enriched by basic Zinc-O,O′-2-ethylhexyldithiophosphates (i-C8-ZnDTP) was investigated in aprotic apolar solvents by integral and structure specific analytical methods. The results let us suppose that the structure of basic i-C8-ZnDTP in apolar aprotic solvents can be described by an Zn3-complex of type ZnO(ZnDTP)2.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bis-(1-chloro-3-phenoxy-prop-2-yl)-sulfanes - Nucleophilic Displacement and Regiochemistry. Separation and Assignment of Diastereomers. Synthesis of Diastereomerically Pure TrithiacyclesThe title compounds 1 were substituted by a series of O-, N- and S-nucleophiles (H2O solvolysis, AgOAc, NaN3, KSCN, NaSPh, thiourea). A strong tendency to β-elimination of HCl depending on the kind of the attacking nucleophile was found. In most cases no regioisomerization could be detected in the isolated products of the nucleophilic displacement. Best results were obtained with sulfur nucleophiles. The separation of the diastereomeric mixture of the p-kresyl derivative 1b into the individual diastereomers 1bA and 1bB in a preparative scale was achieved. These 3-thia-1,5-dichlorides and several products of substitution could be assigned to the meso- or (±)-form by examination of the stereochemistry and symmetry of the corresponding sulfoxides.The 1,5-dimercapto derivatives 8 are convenient as structural units for the synthesis of diastereomerically pure cis- or trans-disubstituted trithiacycles e.g. 15bA, 15bB. The (±)-form of the 4,6-disubstituted 2,5,8-trithia[9]-(2,6)-pyridinophane 16bA was characterized by X-ray crystal structure determination.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 46 (1995), S. 405-409 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion inspection in aircraft constructionThe inspections required on an aircraft during its operational phase are determined largely by the materials and constructions used. Practical experience has shown that corrosion can generally not be prevented on metallic aircraft structures, even if the surface protection systems have been chosen with great care. Constructions and materials used on aircraft and the result types of corrosion are described and the inspection concept is explained on the basis of this. Finally, typical inspection tasks are presented and the measurement results obtained with different NDT methods are presented and discussed.
    Notes: Die erforderlichen Inspektionen an einem Flugzeug in der Nutzungsphase werden wesentlich durch die verwendeten Werkstoffe und Bauweisen bestimmt. Die praktischen Erfahrungen zeigen, daß an metallischen Leichtbaustrukturen Korrosion generell nicht zu verhindern ist, auch bei sorgfältigster Auswahl der Oberflächenschutzsysteme, Luftfahrtspezifische Bauweisen und Werkstoffe und daraus resultierende Korrosionsarten werden vorgestellt. Darauf aufbauend wird das Inspektionskonzept erläutert. Anschließend werden typische Inspektionsaufgaben gezeigt und die Meßergebnisse mit verschiedenen zerstörungsfreien Prüfverfahren dargestellt und diskutiert.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 48 (1997), S. 207-215 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigation on stress corrosion cracking of austenitic steels in cold chloride solutionsAt ambient temperatures of about 25°C austenitic chromium nickel steels can suffer stress corrosion in media with a concentration of both hydrogen ions and chloride ions exceeding 1 mol/L or in strongly concentrated chloride solutions. With the aid of constant strain rate testing and with U-bend specimens the parameters of this types of corrosion were investigated. Contrary to the situation with the acid solutions, the reproducibility of test results with the concentrated chloride solution was found to be low. The formation of martensite by cold working was found to be essential. The corrosion susceptibility decreases with increasing nickel content.Stress corrosion takes place within small critical potential ranges without a limit to more positive potentials as this is the case of stress corrosion with hot media. These potential ranges are widened with increasing cold working especially in the case of strongly grinding or cyclic loading in the plastic range.Corrosion cracking was observed with solutions of MgCl2, LiCl, with a less amount with NaCl, but not with ZnCl2. The concentration of chloride ions have an effect for solutions with a given kind of salt, but not for different salt solutions.
    Notes: Bei austenitischen Chrom-Nickel-Stählen kann transkristalline Spannungsrißkorrosion bei 25°C auftreten, wenn sowohl die Wasserstoffionen- als auch die Chloridionen-Konzentration etwa 1 mol/L überschreiten oder wenn stark konzentrierte Chloridlösungen vorliegen. Die Parameter dieser Korrosion wurden mit CERT-Versuchen und mit Bügelproben untersucht. Im Gegensatz zu den sauren Lösungen ist die Reproduzierbarkeit bei den konzentrierten Lösungen gering, wobei im wesentlichen die Bildung von Verformungsmartensit die Korrosionsanfälligkeit bestimmt, die mit ansteigendem Nickelgehalt abnimmt.Die Spannungsrißkorrosion findet in begrenzten Potentialbereichen statt und ist im Gegensatz zu der Spannungsrißkorrosion in warmer Medien zu positiveren Potentialen hin begrenzt. Die Potentialbereiche können mit zunehmender Kaltverformung ausgeweitet werden, wobei eine grobe Schleifbehandlung und zyklische Belastungen im plastischen Bereich die Rißbildung begünstigen.Rißbildung wurde in Lösungen mit MgCl2, LiCl und im geringen Ausmaß auch mit NaCl, nicht aber mit ZnCl2 beobachtet, wobei die Konzentration der Chlorid-Ionen nur innerhalb einer Salzart, nicht aber bei den verschiedenen Lösungen einen erkennbaren Einfluß hat.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 46 (1995), S. 607-607 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 48 (1997), S. 243-251 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion of parts used for microelectronics applicationsManifestations of corrosion on parts used in microelectronics occur for different reasons and are frequently described in literature. They are not only caused by operational circumstances but are also favoured by the production process. Investigations have been carried out to ascertain the cause of the failure of several circuit boards used in the operation electronics of the preparation unit for kitchen waste water. During microscopic and electronmicroscopic observations of failed circuit boards, different corrosion types have been found, mainly on the surface of a commonly used Sn-Pb-alloy. Hence, potentiostatic and free-corrosion experiments under laboratory conditions have been performed using the employed Sn-Pb-alloy. In order to simulate the increased concentration of harmful substances at the surface of the boards, the medium used contained a high percentage of the substances found in the surroundings of the unit. From the measured values of current density for different potentials and the observed corrosion on the sample's surface, conclusions as to the reported failure of the electrical operation system have been made. During the experiments under laboratory conditions, manifestations of corrosion similar to those found on the surface of the failed circuit boards have been observed. Based on these results, it seems likely that pitting and selective corrosion of the Sn-Pb-alloy led to the failure of the investigated circuit boards and, therefore, of the operation electronics.
    Notes: Korrosionserscheinungen an Bauteilen der Mikroelektronik treten aus unterschiedlichen Gründen auf und sind in der Literatur beschrieben. Sie werden nicht nur durch die Betriebsumstände hervorgerufen, sondern werden nicht selten auch durch die Fertigung begünstigt. Untersuchungen zum Ausfall mehrerer Platten, die in der Steuerungselektronik einer Fettaufbereitungsanlage für Großküchenabwässer zum Einsatz gekommen sind, wurden durchgeführt. Bei der licht- und elektronenmikroskopischen Betrachtung der ausgefallenen Platine wurden verschiedene Korrosionserscheinungen gefunden, die hauptsächlich an dem eingesetzten Lötwerkstoff auftraten. Aus diesem Grund sind an der als Lötstoff eingesetzten Zinn-Blei-Legierung unter Laborbedingungen potentiostatische Halteversuche und Versuche hei freier Korrosion mit Medien durchgeführt warden, welche die Schadstoffe der Umgebungsluft der Anlage in erhöhten Mengen beinhalten, um damit ein Aufkonzentrieren an den Oberflächen der Platine zu simulieren. Anhand der ermittelten Stromdichte-Werte für verschiedene Potentiale und der Korrosionserscheinungen an den Proben werden Rückschlüsse auf den vorliegenden Schadensfall gezogen. Bei den unter Laborbedingungen durchgeführten Versuchen werden ähnliche Korrosionserscheinungen beobachtet, wie sie an den Bauelementen der ausgefallenen Platinen gefunden wurden. Es wird aufgrund der vorliegenden Ergebnisse Vermutet daß Lochfraß und selektive Korrosion der Sn-Pb-Legierung ursächlich für den Ausfall der untersuchten Platinen der Steuerungselektronik ist.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...