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  • Chemistry  (39)
  • Inorganic Chemistry  (28)
  • Arenkomplexe  (1)
  • 1995-1999  (39)
  • 1
    Digitale Medien
    Digitale Medien
    Se2NBr3, Se2NCl5, Se2NCl-6: New Nitride Halides of Selenium(III) and Selenium(IV) (1996)
    Weinheim : Wiley-Blackwell
    Chemistry - A European Journal 2 (1996), S. 1373-1378 
    Details
    ISSN: 0947-6539
    Schlagwort(e): ab initio calculations ; crystal structure ; halogen compounds ; nitrides ; selenium compounds ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Se2NBr3, a planar molecule shaped liked dividers, was formed by the reaction of SeBr4 with N(SiMe3)3, which reduced the selenium to the trivalent state. Under the same conditions, Se2NCl5 was obtained by the reaction of SeCl4 with N(SiMe3)3, retaining the tetravalent state of selenium. The molecule is formed by two edge-sharing pseudotrigonal bipyramids with selenium as their central atoms. Se2NCl5 reacts with PPh4Cl to form the Se2NCl-6 ion by the addition of a Cl- ion to only one of the two selenium atoms, resulting in pseudooctahedral coordination of this atom. Ab initio calculations for all the compounds reported confirm the experimentally determined structures.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/chem.19960021108
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  • 2
    Digitale Medien
    Digitale Medien
    Komplexe von Halogenid-Ionen mit Diiodacetylen. Die Kristallstrukturen von PPh4[X(I-C≡C-I)2] mit X = Cl, Br, I (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 259-262 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Halide complexes of diiodacetylene ; Crystal structures ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Complexes of Halide Ions with Diiodoacetylene. The Crystal Structures of PPh4[X(I-C≡C-I)2] with X = Cl, Br, IThe complexes PPh4[X(I-C≡C-I)2] with X = Cl (1), Br (2), and I (3) have been prepared from the phosphonium salts PPh4X and 1-C≡C-I in dichloromethane solutions. 1-3 form colourless crystals, which according to crystal structure analysis crystallize isotypically in the space group P421m with two formula units per unit cell. The diiodacetylenes are coordinated by the halide ions X- in a distorted tetragonal fashion, the I-C≡C-I molecules being in μ2-bridging function. Thus, a polymeric anionic network [X(I-C≡C-I)2]nn- with a layered structure results.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961290224
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  • 3
    Digitale Medien
    Digitale Medien
    Synthese und Kristallstrukturen der Amido-Komplexe [Na(12-Krone-4)2][M{N(SiMe3)2}3] mit M = Mn, Fe und CoHerrn Prof. Dr. G. Seitz zum 60. Geburtstag gewidmet. (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 715-719 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Amido Complexes ; Manganese Compounds ; Iron Compounds ; Cobalt Compounds ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Syntheses and Crystal Structures of the Amido Complexes [Na(12-Crown-4)2][M{N(SiMe3)2}3] with M = Mn, Fe, and CoThe ionic amido complexes [Na(12-crown-4)2][M[N-(SiMe3)2}3] with M = Mn (1), Fe (2) and Co (3) were prepared by the reaction of M[N(SiMe3)2]2 (M = Mn, Co) and Fe[N-(SiMe3)2]3, respectively, with sodium bis(trimethylsilyl)amide in toluene solution in the presence of 12-crown-4. 1-3 were characterized by IR spectroscopy and by crystal structure determinations. The complexes consist of cations [Na(12-crown-4)2]+ with a sandwich-like structure and anions [M{N(SiMe3)2}3]- in which the metal atoms are planarly coordinate by the three nitrogen atoms of the bis(trimethylsilyl)amido groups.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961290618
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  • 4
    Digitale Medien
    Digitale Medien
    Komplexe von Halogenid-Ionen mit 1-Halogen-2-phenylacetylenen. Kristallstrukturen von PPh4[X(I - C≡C - Ph)4] mit X = Cl, Br, I, von PPh4[Br(Br - C≡C - Ph)4] und von NMe4[F(I - C≡C - Ph)2]Herrn Prof. Dr. H. Brunner zum 60. Geburtstag gewidmet. (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 115-120 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Halide complexes of 1-Halogen-2-phenylacetylenes ; Acetylenes, 1-halogen-2-phenyl-, halide complexes of ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Complexes of Halide Ions with 1-Halogen-2-phenylacetylenes. Crystal Structures of PPh4[X(I - C≡C - Ph)4] with X = Cl, Br, I, of PPh4[Br(Br - C≡C - Ph)4], and of NMe4[F(I - C≡C - Ph)2]Herrn Prof. Dr. H. Brunner zum 60. Geburtstag gewidmet.The complexes PPh4[X(I - C≡C - Ph)4] with X = Cl (1), Br (2), I (3), PPh4[Br(Br - C≡C - Ph)4] (4), and NMe4[F(I - C≡C - Ph)2] (5) were prepared from the corresponding salts PPh4X and NMe4F, respectively, with the 1-halogen-2-phenylacetylenes X - C≡C - Ph (X = Br, I) in dichloromethane solutions. 1 - 5 form colourless crystals, which were characterized by vibrational spectroscopy. According to the crystal structure determinations the halide ions in 1 - 4 are coordinated by the halogen atoms of the 1-halogen-2-phenylacetylenes in a tetragonal-pyramidal fashion. The fluoride ion in 5 is only twofold coordinated with a bond angle I - F - I of 110.45°.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961290121
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  • 5
    Digitale Medien
    Digitale Medien
    Synthese, Eigenschaften und Kristallstrukturen der Titan(III)-Amido-Komplexe Ti[N(SiMe3)2]3, [TiCl2{N(SiMe3)2}(THF)2] und [Na(12-Krone-4)2][TiCl2{N(SiMe3)2}2] (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 1401-1405 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Amido complexes ; Titanium(III) compounds ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Syntheses, Properties, and Crystal Structures of the Titanium(III) Amido Complexes Ti[N(SiMe3)2]3, [TiCl2{N(SiMe3)2}(THF)2], and [Na(12-Crown-4)2][TiCl2{N(SiMe3)2}2]TiCl3(THF)3 reacts with NaN(SiMe3)2 to furnish [TiCl2{N(SiMe3)2}(THF)2] (1), whereas in the presence of 12-crown-4 the ionic amido complex [Na(12-crown-4)2][TiCl2{N(SiMe3)2}2] (5) is obtained besides [Na(12-crown-4)2][TiCl4(THF)] (4). On the other hand, the titanium(III) amido complex Ti[N(SiMe3)2]3 (2), the crystal structure of which was solved, reacts with NaN(SiMe3)2 in the presence of 12-crown-4 with deprotonation of one of the methyl groups to give the carbometalated complex [Na(12-crown-4)2][Ti{N(SiMe3)2}2{N(SiMe 3CH2)}] (3).
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961291115
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  • 6
    Digitale Medien
    Digitale Medien
    Phosphaniminato-Komplexe des Arsens. Kristallstrukturen von [AsCl(NPMe3)]2Cl2, [AsCl(NPMe3)2SbCl4]SbCl6 und [AsCl(NPMe3)2SnCl4] · CH3CNHerrn Prof. Dr. H. J. Bestmann zum 70. Geburtstag gewidmet. (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 109-113 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Phosphane iminato complexes ; Arsenic compounds ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Phosphane Iminato Complexes of Arsenic. Crystal Structures of [AsCl(NPMe3)]2Cl2, [AsCl(NPMe3)2SbCl4]SbCl6, and [AsCl(NPMe3)2SnCl4] · CH3CN[AsCl(NPMe3)]2Cl2 (1) was prepared by the reaction of arsenic trichloride with the silylated phosphane imine Me3-SiNPMe3 in acetonitrile solution. According to the crystal structure determination, 1 has an ionic structure with [AsCl(NPMe3)]22+ ions, in which the As atoms are linked by the μ2-N atoms of the NPMe3- groups. Compound 1 reacts with antimony pentachloride to give [AsCl(NP-Me3)2SbCl4]+SbCl6- (2), with tin tetrachloride to form [AsCl(NPMe3)2SnCl4] (3), which is isoelectronic to the cation of 2. In 2 and 3 AsCl(NPMe3)2 acts as a chelating agent forming and , respectively, four-membered ring structures.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961290120
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  • 7
    Digitale Medien
    Digitale Medien
    Zinkorganische Phosphaniminato-Komplexe mit Heterocuban-StrukturHerrn Prof. Dr. Armin Berndt zum 60. Geburtstag gewidmet. (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 1621-1625 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Organo-zinc compounds ; Phosphaneiminato complexes ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Organo-Zinc Phosphaneiminato Complexes with Heterocubane StructureThe organo-zinc heterocubanes [ZnR(NPMe3)]4 with R = CH3 (1) and n-C4H9 (2) were prepared by the reaction of [ZnBr(NPMe3)]4 with MeLi and nBuLi, respectively, in hexane solution. In a similar reaction of nBuLi with [ZnI(NPMe3]4 the phosphaneiminato complex [Zn4I(nBu)4(NPMe3)3] (3) is formed. 1-3 were characterized by IR, NMR and MS spectroscopy, and by crystal-structure determinations. 1 and 2 possess heterocubane structures in which the zinc atoms are linked via μ3-N bridges of the phosphaneiminato groups, and all bond angles in the Zn4N4 core are close to 90°. A distorted heterocubane structure is observed for 3 with one of the NPMe3 moieties replaced by an iodine atom.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961291232
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  • 8
    Digitale Medien
    Digitale Medien
    Lithiierte Phosphanimine. Synthese und Kristallstrukturen von [LiCH2PMe2NSiMe3]4 und [LiCMe2P(iPr)2NSiMe3]2 (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 253-257 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Lithiated phosphane imines ; Phosphane imines, lithiated ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Lithiated Phosphane Imines. Synthesis and Crystal Structures of [LiCH2PMe2NSiMe3]4 and [LiCMe2P(iPr)2NSiMe3]2The title compounds were prepared by the reaction of Me3-SiNPMe3 and Me3SiNP(iPr)3, respectively, with n-Butylli-thium at 20°C in n-hexane solution. They form white, moisture- and oxygen-sensitive crystals, which were characterized by IR spectroscopy and by crystal structure determinations. - [LiCH2PMe2NSiMe3]4 (1) forms a Li4 tetrahedron, the faces of which are capped with CH2 groups with average Li-C distances of 233 and 251 pm, while the nitrogen atoms occupy the corners of the Li4 tetrahedron. - [LiCMe2P(iPr)2N-SiMe3]2 (2) forms molecules of symmetry C2 in which the lithium atoms have coordination number three by two carbon atoms and one nitrogen atom with Li-C distances of 215.2 and 237.9 pm and Li-N of 192.8 pm.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19961290223
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  • 9
    Digitale Medien
    Digitale Medien
    Die Kristallstrukturen von (NH4)2[ReCl6], [ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN und [ReCl4(18-Krone-6)] (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 525-530 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Rhenium Complexes ; Syntheses ; IR spectra ; Crystal Structures ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The Crystal Structures of (NH4)2[ReCl6], [ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN and [ReCl4(18)(Crown-6)]Brown single crystals of (NH4)2[ReCl6] are formed by the reaction of NH4Cl with ReCl5 in a suspension of diethylether. [ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN crystallizes as brown crystal plates from a solution of ReCl5 in acetonitrile. Lustrous green single crystals of [ReCl4(18-crown-6)] are obtained by the reaction of 18-crown-6 with ReCl5 in a dichloromethane suspension. All rhenium compounds are characterized by IR spectroscopy and by crystal structure determinations.(NH4)2[ReCl6]: Space group Fm3m, Z = 4, 75 observed unique reflections, R = 0.01. Lattice constant at -70°C: a = 989.0(1) pm. The compound crystallizes in the (NH4)2[PtCl6] type, the Re—Cl distance is 235.5(1) pm.[ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN: Space group P1, Z = 1, 2459 observed unique reflections, R = 0.12. Lattice dimensions at -60°C: a = 859.0(1), b = 974.2(7), c = 1287.3(7) pm, α = 102.69(5)°, b̃ = 105.24(7)°, γ = 102.25(8)°. The structure consists of two symmetry-independent [ReCl2(CH3CN)4]+ ions with trans chlorine atoms, [ReCl6]2- ions, and included acetonitrile molecules. In the cations the Re—Cl bond lengths are 233 pm in average, in the anion they are 235 pm in average.[ReCl4(18-crown-6)]: Space group P21/n, Z = 4, 3 633 observed unique reflections, R = 0.06. Lattice dimensions at -70°C: a = 1040.2(4), b = 1794.7(5), c = 1090.0(5) pm, b̃ = 108.91(4)°. The compound forms a molecular structure, in which the rhenium atom is octahedrally coordinated by the four chlorine atoms and by two oxygen atoms of the crown ether molecule.
    Notizen: Braune Einkristalle von (NH4)2[ReCl6] entstehen durch Reaktion von NH4Cl mit ReCl5 in einer Diethylethersuspension. [ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN kristallisiert als braune Kristallplättchen aus einer Lösung von ReCl5 in Acetonitril. Leuchtend grüne Einkristalle von [ReCl4(18-Krone-6)] entstehen durch Reaktion von 18-Krone-6 mit ReCl5 in einer Dichlormethansuspension. Die drei Rhenium-Verbindungen werden durch ihre IR-Spektren und durch Kristallstrukturanalysen charakterisiert.(NH4)2[ReCl6]: Raumgruppe Fm3m, Z = 4, 75 unabhängige beobachtete Reflexe, R = 0,01. Gitterkonstante bei -70°C: a = 989,0(1) pm. Die Verbindung kristallisiert im (NH4)2[PtCl6]-Typ, der Re—Cl-Abstand beträgt 235,5(1) pm.[ReCl2(CH3CN)4]2[ReCl6] · 2CH3CN: Raumgruppe P1, Z = 1, 2459 beobachtete unabhängige Reflexe, R = 0,12. Gitterkonstanten bei -60°C: a = 859,0(1); b = 974,2(7); c = 1287,3(7) pm, α = 102,69(5)°; b̃ = 105,24(7)°; γ = 102,25(8)°. Die Struktur besteht aus zwei symmetrieunabhängigen [ReCl2(CH3CN)4]+-Ionen mit trans-ständigen Chloratomen, [ReCl6]2--Ionen und eingelagerten Acetonitrilmolekülen. In den Kationen betragen die Re—Cl-Abstände im Mittel 233 pm, im Anion im Mittel 235 pm.[ReCl4(18-Krone-6)]: Raumgruppe P21/n, Z = 4, 3 633 beobachtete unabhängige Reflexe, R = 0,06. Gitterkonstanten bei -70°C: a = 1040,2(4); b = 1794,7(5); c = 1090,0(5) pm; b̃ = 108,91(4)°. Die Verbindung bildet eine Molekülstruktur, in der das Rheniumatom oktaedrisch von den vier Chloratomen und von zwei Sauerstoffatomen des Kronenethers koordiniert ist.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19956210404
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  • 10
    Digitale Medien
    Digitale Medien
    Synthese und Kristallstruktur des Selenyl-Phosphaniminato-Komplexes SeO(NPPh3)2 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1171-1174 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Selenium ; Phosphorane Iminato Complex of Selenium ; Synthesis ; IR Spectrum ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Synthesis and Crystal Structure of the Selenyl-Phosphoraneiminato Complex SeO(NPPh3)2SeO(NPPh3)2 has been prepared from SeO2 and Me3SiNPPh3 in a SeO2 suspension in acetonitrile, forming colourless crystals. The compound is characterized by IR spectroscopy and by a crystal structure determination. Space group P1, Z = 2, structure solution with 5 344 observed unique reflections, R = 0.064. Lattice dimensions at -40°C: a = 931.6, b = 947.6, c = 1 762 pm, α = 77.50°, β = 81.78°, γ = 79.23°. The compound forms monomeric molecules in which the selenium atom is ϕ-tetrahedrally surrounded with bond lengths SeO = 161.7 pm and SeN = 179.9 and 181.6 pm.
    Notizen: SeO(NPPh3)2 entsteht in Form farbloser Kristalle bei der Reaktion einer Suspension von SeO2 mit Me3SiNPPh3 in Acetonitril. Die Verbindung wird durch das IR-Spektrum und durch eine Kristallstrukturanalyse charakterisiert. Raumgruppe P1, Z = 2, Strukturlösung mit 5 344 beobachteten unabhängigen Reflexen, R = 0,064. Gitterkonstanten bei -40°C: a = 931,6; b = 947,6; c = 1 762 pm, α = 77,50°, β = 81,78°, γ = 79,23°. Die Verbindung bildet monomere Moleküle, in denen das Selenatom verzerrt ϕ-tetraedrisch umgeben ist mit Abständen SeO = 161,7 pm und SeN = 179,9 und 181,6 pm.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19956210709
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