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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 37-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments are reported in which the drag of single liquid droplets settling in a tall column of another lighter immiscible liquid are measured. The experimental data for the eight pairs of liquids that were tested covered a range of droplet Reynolds numbers from 10-3 to 104. Two regimes of droplet settling were encountered. In the first regime, the droplets remained spherical, and the drag agreed very well with established solid sphere drag models. In the second regime, the droplets became deformed and oscillated; the drag was found to depart suddenly from predictions of spherical models and to increase with increasing Reynolds number. Empirical models for the point of departure from spherical drag and the coefficient of drag in the unstable regime are derived.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 383-388 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bifurcation problems with slowly varying control parameters are of interest in several research areas, including catalyst deactivation, combustion, and lasers and other nonlinear optical devices. Significant theoretical work has been devoted to the study of these dynamic phenomena, but very little directly relevant experimental information is currently available. Results are presented here from an experimental study of the dynamic behavior of a catalytic reaction system due to a deliberately slowly varied control parameter. Attention is focused on the dynamics due to slow passage through simple limit and Hopf points.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Identification and characterization of coupled diffusional and electrochemical kinetics effects was achieved under potentiostatic anodic dissolution conditions. A one-dimensional artificial pit geometry with sample wire electrodes embedded in an inert support exposed to NaCl solutions was used to study the dissolution of stainless steel and highnickel Alloy 600. Multiple steady states for both materials were determined at conditions where the diffusional transport rates balanced the electrochemical rate of dissolution at the surface of the wire electrode. A theoretical transport model was developed to quantitatively explain the observed multiple steady state phenomena.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1261-1271 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study clarifies and quantifies factors which increase the ductility of a low-molecular-weight propylene homopolymer having an intrinsic viscosity of 0.89 dl/g. The tensile behavior of homopolymer/ethylene-propylene rubber (EPR) blends was studied from the viewpoint of the associated molecular structure of EPR and its compatibility with the homopolymer. When EPR is “dissolved” in a homopolymer, the glass transition temperature (Tg) of the amorphous phase of a homopolymer was found to shift to a lower temperature, with homopolymer/EPR compatibility being subsequently evaluated using this shift, i.e., Δtg. Results show two conditions are required to improve the ductility of the low-molecular weight propylene homopolymer: ΔTg must be ≥ 3°C and ≥ 30 wt% EPR must be blended with the homopolymer.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 954-964 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We have obtained values for interaction second viral coefficients of the helium-carbon dioxide system in the range 230 ≤ T/K ≤ 300. Our experimental technique is essentially the Burnett mixing method described by Hall and Eubank (1973, 1974). We have modified the analysis to account for higher-order effects and to detect significant systematic errors. We also report virial coefficients for the pure components: helium in the range 100 ≤ T/K ≤ 300 and carbon dioxide at 300 K.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 279-285 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A revised version of a recently proposed free-volume theory of polymer-solvent diffusion is introduced and evaluated using experimental diffusivity data collected over wide temperature and concentration ranges. The theory accurately predicts the large temperature and concentration variations typically observed for polymer-solvent diffusion coefficients.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 854-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Following secondary recovery processes in conventional light oil reservoirs, more than half the original oil in place may remain trapped as a discontinuous phase. During the previous recovery processes these oil ganglia have been pinched off by capillary forces and remain immobile while the continuous phase which surrounds them is able to flow freely. Furthermore if a portion of this oil is mobilized in a tertiary recovery process the conditions required to apply Darcy's equation to the flow of either phase are violated. These are also problems which are encountered during in-situ recovery techniques in tar sands where the mobilization of the heavy oil occurs as a discontinuous phase. In this paper the relevant flow equations are derived. Also a parameter is deduced which directly determines the criterion for mobilization.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Forced Rayleigh scattering, a relatively recently developed optical technique, is used to measure tracer diffusion coefficients in polymer-solvent mixtures near the system glass transition temperature, Tg. The technique has a wider range of potential application than has yet been realized, and so is presented in some detail. The objectives were to obtain data necessary to scrutinize free volume theory, and to understand so-called anomalous, non-Fickian diffusion effects observed by others in polymer-solvent mixtures near Tg. Data on dye tracer diffusion coefficients in the systems polyvinyl acetate-toluene, polystyrene-toluene, and polystyrene-tri-m-tolyl phosphate were obtained over a polymer concentration range from infinite dilution to 96 wt. %. Small molecule diffusion coefficients are seen to vary by as much as nine orders of magnitude (10-14 to 10-5 cm2/s) over this concentration range. The data are in reasonable accord with expectations based on the Duda-Vrentas version of free-volume theory.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1659-1666 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental results are reported for equilibrium adsorption and diffusivities of CH4, C2H6 and CO2 in type A zeolite containing mixed Na and K cations ranging from 0 to 100% in composition, at two temperatures and 1 atm. Two simple theoretical solutions are given for the diffusivity. One is for diffusion with pore (aperture) blocking using the effective medium approximation, which is readily available from the literature on percolation theory. The other is a kinetic solution derived in this work for cavities containing heterogeneous sites, which is a case where the percolation theory is not applicable. The equilibrium adsorption results show that K+ has a preference for the aperture (or pore-blocking) sites (site type II), and these results are interpreted by the bond percolation theory. The diffusivity results are successfully interpreted by the poreblocking theory in zeolites containing less than 25% K+ and by the kinetic theory for zeolites with higher K+ contents.
    Additional Material: 11 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 365-367 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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