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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 656-660 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By using a special surface thermocouple Moore and Mesler have measured large temperature fluctuations during nucleate boiling of water on chromel P surface. They found that the temperature dropped 20° to 30°F. in about 2 msec. but required 10 to 20 msec. to recover. They have postulated that the surface was cooled during initial bubble growth by evaporation of a microlayer into the bubble. To test this hypothesis a technique was developed to photograph a bubble growing from an artificial site as the surface temperature was measured.Temperature fluctuations were recorded on an oscilloscope which automatically triggered the bubble photographs by means of a time delay unit and flash tube. Photographs of bubbles were taken at 1 μsec. exposure time and ranged from about 10 μsec. after the start of the temperature drop to about 1 msec. before the start of another cycle. The photographs show that the surface cools during bubble growth and recovers during bubble departure.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 304-310 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed study has been made of the excess viscosity of dense-phase aragon, deuterium, helium-3, helium-4, para and normal hydrogen, neon, and nitrogen and of the excess thermal conductivity of normal hydrogen. A definite temperature dependence for the excess viscosity vs. density has been shown to exist for argon, helium-4, hydrogen, and nitrogen and to be indicated for deuterium. The existing thermal conductivity data for hydrogen have been examined. A theoretical analysis for the qualitative behavior of excess thermal conductivity is given. The critical point viscosity values for all the species are given. Graphs, together with references to 1-atm. data, are presented for computation of the transport properties.
    Additional Material: 10 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 144-146 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 229-240 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study is concerned with the derivation and application of the finite-stage transport concept for modeling residence time distributions (RTD's) originally proposed by Adler and Hovorka (1961). This six-parameter model is shown to be more versatile and accurate than the common two-parameter tanks-in-series or axial dispersion models. Radioactive tracer results are given for a number of particulate unit processes with special emphasis on wet-discharge ball mills.
    Additional Material: 21 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2177-2186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approximate steady-state method is devised for computing the flow field in a baffled, impeller-stirred tank reactor. The flow field in a cylindrical tank with a 45° pitched-blade impeller rotating at 100 rpm and four stationary rectangular side-wall baffles is simulated using a new approximate steady-state approach. The method provides an alternative to a full unsteady Navier-Stokes simulation. The new steady-state analysis involves accurately defining the geometry of the mixing tank using a multiblock grid technique. The flow is solved from a rotating frame of reference for a single position of the impeller relative to the side-wall baffles. The steady-state numerical results are then spatially averaged and compared with time-averaged data obtained experimentally using laser Dopler velocimetry (LDV). Spatially averaged numerical predictions obtained using this approximate steady-state method for the radial and axial velocity components agree well with the LDV data. The predicted magnitude of the tangential velocity component, however, is higher than the experimentally measured values. Closer agreement of the tangential velocities with experimental values is obtained using a finer grid and it is found that a relatively fine grid is needed for accurately predicting the tangential velocity magnitude. Use of this approximate steady-state method allows designers of mixing vessels to obtain flow-field results for baffled vessels much more efficiently than using full unsteady Navier-Stokes simulations.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1231-1232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 369-377 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical and kinetics model is presented for reactions catalyzed by solid surfaces where both competitive and noncompetitive adsorption take place, a situation that may be general in reactions between large and small molecules catalyzed by solid surfaces.In the adsorption of large molecules steric hindrance or multiple site adsorption cause maximum surface coverage of such molecules before all sites are occupied. This does not, however, preclude further adsorption of small molecules on the remaining isolated vacant sites nor does it preclude further surface reaction. The overall reaction model for such conditions may be expressed as This particular model has been evaluated for the catalytic hydrogenation of propylene and isobutylene with the expectation that it may be useful in reactions that are of industrial importance. A reaction model based on either competitive adsorption or noncompetitive adsorption alone fails to correlate the experimental data.In these two reactions maximum rates occur at olefin concentrations below 5 mole % and the catalytic adsorption constants for the olefins are a hundredfold greater than for hydrogen. This reaction model is similar to that proposed by Bond and Turkevich (15), who have further demonstrated through the deuteration of propylene that the actual mechanism of the reaction is much more complicated.
    Additional Material: 15 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 445-452 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Atactic polystyrene was molded at pressures up to 3000 atmospheres, and the effects of this pressure history were studied by permeability measurements using helium, neon, and argon as probe molecules. The permeabilities were significantly reduced by molding at higher pressures. The diffusion coefficients decreased monotonically with molding pressure, reflecting more extensive interchain cohesion. In contrast, the solubility coefficients showed a broad minimum around a molding pressure of 1000 atm, indicating that changes in local order were induced by higher pressures. These changes were shown to affect permeation, mechanical characteristics, and other properties. An optimum molding pressure somewhat below 1000 atm is indicated for polystyrene.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 310-312 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 536-538 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Semirigorous equations are developed for flow of flashing liquids in pipe lines. These relations are applied to the flow of hydrogen, and computed correlations are presented for the pressure drop and vapor fraction. The calculations have been carried out as functions of the parameters: diameter, 3/8 to 4 in.; mass rate per unit area, 0.0528 to 682 lb./(sq. ft.) (sec.); pressure, 14 to 30 lb./sq. in. abs.; vapor fraction, 0.005 to 0.65; and heat leak, equivalent to 0 to 0.0224 B.t.u./(sq. ft.) (sec.) for a 3/4-in. line.
    Additional Material: 2 Ill.
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