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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 548-552 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the diffusion coefficients of hydrogen and methane in strong aqueous electrolytes have been made with the use of the diaphragm cell method. The variation of the diffusion coefficients with electrolyte concentration, type of ion, and temperature has been studied over the electrolyte concentration range zero to saturated, and for temperatures in the range 25° to 65°C.The results have been interpreted with the Eyring rate theory. The presence of ions in water increases the activation energy for diffusion which results in a decrease in the diffusion coefficient. The increase in activation energy is represented by terms that are additive for the ions involved. The influence of ions on the diffusion coefficient increases rapidly with ionic charge, but seems to be little affected by temperature or solute for the systems studied.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 507-514 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An expression is derived for the analysis of gas-phase mass transport in porous media in the presence of gradients in pressure and mole fraction. The behavior of porous media is contrasted with that of capillary tubes. A continuous-flow diffusion and permeation apparatus was employed for studies of mass transport in a fritted glass diaphragm. Measurements were obtained at varying levels of pressure and cover both isobaric binary diffusion and the permeation of pure gases and gas mixtures. These experimental results and previous data obtained by Hewitt and Sharratt and by Mason, et al. bear out the form of the equation and successfully provide independent checks of the three constants necessary to characterize a given porous medium.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 183-188 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Part I of this work develops a corresponding states theory for fluid mixtures. A greater predictive capability for the thermodynamic properties of mixtures is achieved through three developments: 1. The theretical validity of the pseudocritical method is established. 2. The theory is founded on well-defined assumptions. 3. The composition dependence of the scaling parameters (pseudocritical constants) is developed from rigorus mixing rules. Implementation of the new method is discussed in Part II.
    Additional Material: 1 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 1284-1285 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 944-951 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With the development of relatively inexpensive control computers and on-stream analyzers, on-line dynamic optimization of nonlinear, multistage systems has become more feasible. Investigators have been concerned with the static optimization and control of single-stage and multistage systems, but few have considered the optimization of a multistage system whose behavior is nonstatic owing to stochastic changes in its input and environment, and whose optimal control policy is time varying.This paper looks at the problem of dynamic optimization as it applies to the analysis of a multistage continuous stirred-tank reactor system. A variational approach, in which the physical restraints on the manipulatable variables are included by a parametric representation, led to a bang-bang, sampled-data, optimal control law, or an equivalent analytical expression for continuous optimal control. Inclusion of the inequality relationships, specifying amplitude constraints on the manipulatable variables by a penalty function, resulted in a set of nonlinear Euler-Lagrange equations specifying the control law.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 334-340 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented by which a particular class of interacting linear multivariable systems may be decoupled into independent, first-order subsystems containing a single output as a function of a single manipulatable input and a single measurable input. This is accomplished by application of compensators in the form of feedforward amplifiers and proportional plus derivative feedback controllers. Simultaneous application of a stabilizing feedback controller and a feedforward amplifier to each decoupled subsystem results in perfect control of system outputs yi (t), that is, yi (t) = 0 for all t ≧ 0. In addition, the compensating device contains degrees of freedom that make it possible to set output forms within any limits desired in the case that subsystem feedforward controllers operate imperfectly, and obtain better fit between the linear system model, which forms the basis for controller design, and the corresponding nonlinear system model.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 340-345 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general method, given in a companion paper, by which an interacting linear multivariable system may be decoupled into independent subsystems, is applied to a continuous flow stirred-tank reactor. The form of the compensating controllers required for the physical system is obtained. It is then verified numerically that noninteraction is achieved, as postulated, by simulation of the linear model with compensating control on the analog computer.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 243-245 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 9
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design of vapor recovery processes requires very accurate vapor-liquid equilibria data. In this work the problem is attacked from both an experimental and a correlational viewpoint, and the methane-n-hexane system is chosen for study. A predictive model for vapor-liquid equilibrium aids in the interpretation of the experimental measurements, and data acquired in this study agree closely with the theoretical predictions. Maximum deviation between calculated and experimental equilibrium ratios (yi/xi) is 8.5% with average absolute deviations of 3% for n-hexane and 0.1% for methane. Several procedures are described for checking the accuracy of experimental VLE data when a heavy vapor is present at low concentrations in the gas phase. Several potential sources of experimental error are also identified and discussed.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 825-826 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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