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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 93-98 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The permeation rate of hydrogen through cylindrical membranes of type 321 stainless steel was determined under a wide range of conditions. The pressure was varied from 0.1 to 30.0 atm. and the temperature from 300° to 800°C. Four permeation membranes were used with wall thicknesses of 0.0252, 0.1003, 0.1011, and 0.2475 cm.The permeation rate was found to deviate from the square-root-of-pressure and inverse-thickness relations predicted by the Richardson equation. Slow surface reactions are considered to be the cause of the observed deviations. The permeation data were correlated by a semiempirical interfacial resistance model.Permeation rates were observed to increase with time of membrane exposure to hydrogen. It is believed this resulted from changing surface activity.
    Additional Material: 3 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 968-973 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 392-397 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In gas-metal permeation, diffusion is normally considered to be the rate-controlling step. In addition, the diffusivity is usually taken to be independent of concentration. Under these conditions, the time lag (a characteristic of the system which depends on the time required to achieve steady state flow) is found to be (and theoretically should be) independent of the gas pressure applied to the inlet surface of the metal membrane. Furthermore, the time lag can then be directly related to the diffusivity of the system.In this paper, data on the hydrogen type 321 stainless steel system are presented which show a pronounced effect of pressure on measured values of the time lag. Taken alone, these data can be explained either by a concentration-dependent diffusivity or by resistance to flow at the metal surface. From steady state data it is shown that surface resistance is the better explanation. A model of the permeation process is presented which is consistent with the time lag data, and an estimate is made of the diffusivity of hydrogen in type 321 stainless steel.The variables studied were hydrogen pressure at the entrance surface of the membrane (0.1 to 30.0 atm.), temperature (300° to 800°C.), and membrane wall thickness (0.0252 to 0.2475 cm.).
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 668-677 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanical behavior of various classes of inked and non-inked (dry) open-cell foam rollers has been investigated from stress/strain measurements in compression. Hysteresis, creep, and recovery in dynamic loading were used to differentiate the rollers as to their utility in printing applications. Creep, ∊c(t), and recovery, ∊r(t), were determined in a compression mode from force measurements and strain decay, ∊(t), i.e., Δ∊c(t) = ∊0 - ∊(t) [∊0 = ∊(t = 0)] or ∊c(t) = 2∊0 - ∊(t). The creep function, Δ∊c(t), represents the plastic strain, ∊pl(t = th), and is uniquely defined from the recovery function, Δ∊c(t) = ∊r(t = th), where th is the hold or contact time. The recovery results for a polyurethane ester (PUE) and acrylonitrile/butadiene (AB) rollers (dry/ink), poly(vinylidene fluoride) film (PVF2) (air/vapor) and low-density polyethylene film (LDPE) (air/vapor) were found to fit a master curve of the form Fr(θ) = EXP[-Kr(th)θ] = [∊r(t) - ∊∞(th)]/[∊0(t = O) - ∊∞(th)] at a reduced time of Kr(th)θ {θ = t/th and Kr(th) = k′r(th)th = C0/(th)α-1 (where C0 depends on the material's “dry” or “wet” state, α is a function of the type of material, and ∊∞ is the permanent set). These empirical results are consistent with the observed decreases in print intensity during transfer to a paper substrate and weight changes of the roller, i.e., creep and recovery are important in the printing characteristics of a given roller material. Other factors of importance in the overall transfer and print quality, but of longer-term considerations, are diffusion processes within the polymer and the nature of the polymer (e.g., porosity, chemical constitution, surface and interfacial tensions).
    Additional Material: 8 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 734-742 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: At a fixed vapor pressure p of the penetrant and constant temperature of the experiment, the sorption S = c/p or concentration c of the ethylacetate vapor in the uniaxially strained low density polyethylene (LDPE) increases most rapidly at low strains. If, however, on the basis of strain relaxation one separates the total strain ∊ into an elastic ∊e, and a plastic ∊pl, deformation, one obtains an almost linear increase of the concentration c or sorption S of the sorbate with elastic strain ∊e. The separation of ∊ = ∊e + ∊pl depends very much on the time th the sample is kept elongated and the vapor pressure p of the sorbate. The elastic component decreases and the complementary plastic fraction increases with th and p. An almost stationary state is reached after th of about 1/2 h. The calculation of the diffusion coefficient Ds1 from the first sorption immediately after the stretching is affected by this slow adjustment in the interval 0 ≤ th ≤ ½h and shows a pseudo maximum at a strain of ∊∼ = 10 percent. The first desorption experiment and all the later sorptions and desorptions yield the same DD = DS 〈 DS1 that is the correctly calculated diffusion coefficient D. The coefficient D decreases with the strain ∊ or ∊e in contrast with the expected increase of Da of the amorphous component. Such an increase of Da is expected as a consequence of the fractional free volume (FFV) increase caused by the elongation. According to the FFV concept, a decrease of the measured apparent diffusion coefficient D = ψDa requires that with increasing ∊, the tortuosity factor ψ decreases faster than the increase in Da.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 73-78 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The liquid heat capacities and heats of vaporization of three linear esters of poly(hexamethylene sebacate) with hexylcapped end groups (M(mol. wt.) = 370, 655, and 939) have been determined. The heats of vaporization of the oligomers measured at a mean temperature were corrected to 323.15 to 523.15°K by use of the experimental liquid (melt) heat capacities and the calculated gas heat capacities. The corrected heats of vaporization were fitted to the equation ΔHv = S(T)Mα + I(T), where the temperature dependence of the slope and intercept are represented, respectively, as S(T) = ClnT + Ko and I(T) = a T + bo, and α is an exponent. The results indicate (at corresponding molecular weights and constant temperature) that the ratio of the liquid heat capacities of the oligomer ester and the n-alkane, and similarly the ratio of the heats of vaporization, depend on the number of carboxyl groups in the oligomer ester chain.
    Additional Material: 4 Ill.
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