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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 2059-2062 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Peak nucleate boiling fluxes for liquid oxygen near 1 atm, have been measured on a 0.75-in.-diameter flat polished horizontal platinum surface located in a known, variable magnetic-field gradient that produced steady acceleration (which could be maintained indefinitely) on the oxygen acting in opposition to the earth's gravitation, gE. Measurements were made under condition ranging from net negative (directed away from the heated surface) accelerations of -0.03gE acting on the bulk liquid to the normal accelerations, 1.0gE. The results indicate that at zero g conditions for the bulk liquid, the peak nucleate boiling flux is ∼0.55 of the value at 1.0gE. For bulk-liquid accelerations ranging from ∼0.25 to 1gE, the experimental results confirm the ¼ power dependence of peak flux on acceleration as predicted by various correlations. However, below 0.25gE the peak flux becomes insensitive to the acceleration, varying approximately in proportion to the 1/14 power of the net acceleration. At bulk-liquid conditions of zero g (±0.005gE) the peak plux breaks sharply and falls by a factor of 10 between zero g and -0.03gE (for this apparatus).
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 790-795 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer coefficients have been measured over a range of Reynolds numbers for a solid-vapor mixture of parahydrogen discharging through a heated brass tube below the triple point pressure. A correlation is given which is shown by a formal analysis of a simple model to account for most of the system variables.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 890-897 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are presented for wall temperatures and heat transfer coefficients for solid-vapor mixtures of parahydrogen and nitrogen flowing in an electrically heated straight tube of length 40 times its diameter. These are interpreted by the application of flat plate, constant property boundary-layer theory to models in which the solid particle geometrical distribution takes on simple limiting forms. The observed enhancement of the heat transfer coefficient over that for gas alone traveling at the same velocity is qualitatively predicted as a function of a dimensionless heat flux, the Sterman parameter qw/ρvUλ.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1555-1557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 3-16 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We investigated the effect of concentration on the Brownian diffusion of uncharged rigid spheres. Monosize silica spheres were prepared according to the method of Stöber (1968). The particles were sterically stabilized by chemisorption of stearic alcohol at their surface by the method developed by van Helden (1981).Particle radius was 14.5 nm from electron micrographs of the coated particles. Osmotic pressure measurements of the sterically stabilized particles dispersed in cyclohexane showed that the particles behaved as hard spheres. The measurements agreed well with predictions from the Carnahan-Starling equation over the concentration range 0.0458 〈 φ 〈 0.37 where φ is the volume fraction of the particles in the suspension. Viscosity measurements of silica dispersions were made over the concentration range 0 〈 φ 〈 0.25. The relative viscosity over the range 0 〈 φ 〈 0.2 was fitted by ηr = 1 + 2.4φ + 7.1φ2. The coefficients 2.4 and 7.1 in this equation are in good agreement with the theoretical values of 2.5 and 6.2 obtained by Einstein(1906) and Batchelor(1977), respectively. The Brownian diffusion coefficient of the particles dispersed in cyclohexane was measured over the concentration range 0.0055 〈 φ 〈 0.248 using Taylor's hydrodynamic stability method. A laser fiber-optic system was used to measure the transient concentration profile along the capillary as indicated by a fluorescent dye. This technique offers the advantage of being direct and nonintrusive. The experimental diffusivity data were found to be well described by the generalized Stokes-Einstein equation(Batchelor, 1976) over the entire concentration range studied.
    Additional Material: 12 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 8 (1989), S. 200-205 
    ISSN: 0278-4513
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The venting and control strategies of a Magnesium Grignard formation reaction were assessed by theoretical predictions of the exotherm and the reaction rate, by simple laboratory measurements of the self heat rate, and by Leung's simplified equations and SAFIRE evaluations, based on DIERS methods. SAFIRE computations showed that the 150 mm dia vent was capable of keeping the reactor pressure below its maximum (MAWP) of 860 kPa for the worst-case exotherm.The response to this evidence was to increase safety protection in the automatic control strategy, following a quantified fault tree analysis of the worst-case runaway scenario.
    Additional Material: 2 Ill.
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