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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 251-259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental and analytical study is reported of transient natural convection in a vertical cylinder. For the experiments a cylinder was partially filled with liquid and subjected to a uniform heat flux at the walls. Thermocouples were used to measure the unsteady temperature field within the liquid; dye tracers were used to study flow patterns. Parameters that were varied included the test liquid (water-glycerin mixtures), the liquid depth, and the wall heat flux. A range of Prandtl number from 2 to 8,000, L/D ratio from 1 to 3, and Grashof number from 103 to 1011 were studied, encompassing both laminar and turbulent flow regimes.An analytical model was developed by dividing the system into three regions: a thin boundary layer rising along the heated walls, a mixing region at the top where the boundary layer discharges and mixes with the upper core fluid, and a main core region which slowly falls in plug flow. The temperature of the core fluid was assumed to vary in the vertical direction but not in the horizontal direction. Natural convection boundary-layer equations were modified to allow for a temperature variation at the outer edge of the boundary layer. The model may be used with a step-by-step computational procedure to predict the temperature distribution in the fluid as a function of time for an arbitrary set of conditions. Results computed by using the model were in good agreement with the experimental data.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 412-413 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 7 (1988), S. 259-264 
    ISSN: 0278-4513
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The methodology of the work is discussed. An overview of safety procedures for dealing with high toxic hazard materials is provided.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 12 (1993), S. 92-103 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The chemical industry today is in transition, with increasing emphasis on total quality control along with needs to meet ever more stringent levels of health, safety, and environmental management. Fortunately, these needs are being met by tremendous strides in process monitoring and control instrumentation. Microprocessor-based process sensors, programmable electronic systems (PESs), and precision throttling valves now improve the implementation and maintenance of complex process control strategies, with operators interacting with the process through modern human/machine interfaces. Sophisticated graphical displays and powerful control algorithms aid the operators in their work. Many formerly manual tasks are being automated. Some sources of human error are reduced by the use of PES controls, but these systems introduce new and different potential sources of error, leading to new implementation considerations.Many of the hazard identification and risk assessment methodologies used today are based on techniques that assume independence of failures. However, possibilities for common mode failures and covert faults are greatly increased in process control systems that make use of PES technology. PES controls are interconnected through data highways; use common hardware and software functions in many modules; and may depend on central supervisory control computers for some critical control data. Today, achieving plant safety is a systems issue, requiring an integrated analysis with inputs from each of the disciplines involved in design and operation, as well as the guidance of safety and risk specialists. This article presents a systematic, semi-quantitative approach to total system safety design in which modern programmable electronic monitoring and control systems are integrated with traditional administrative and engineering controls to achieve acceptable levels of operating risk. The philosophy presented is a reflection of the consensus of a group of experienced control system specialists from some ten leading companies.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental program was conducted to study the thermochemical, flammability and toxicological characteristics of uncoated and coated polyisocyanurate foams. The coatings used were fluorinated copolymer and an intumescent material. Flammability testing methods included the XP-2 chamber smoke test, ASTM D-1692, infrared photography, Bureau of Mines penetration test, and a JP-4 fuel combustion chamber. The results of these tests are presented in a companion paper. Combustion and pyrolysis gases were analyzed by gas chromatography and mass spectrometry. The LD-50 and LD-100 tests were performed on Sprague-Dawley rats housed in an environmental chamber. The isocyanurate foam, flourinated-copolymer-coated foam, and the intumescent-coated foam were found to have excellent flammability and insulation characteristics, although smoke development was substantial. The LD-50 values for Sprague-Dawley rats, based on a two-week survival, were approximately 2.0 gm/ft3 for all three materials. Examination indicated an absence of any significant cause of death except carbon monoxide poisoning.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 167-178 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental program was conducted to study the thermochemical and flammability characteristics of an improved polyisocyanurate foam, uncoated and coated either with fluorinated copolymer or an intumescent material. Testing methods included thermal analysis; scanning electron microscopy; infrared photography; infrared spectroscopy; HLT-15, ASTM D-1692, Bureau of Mines Penetration, and XP-2 smoke chamber flammability tests; limiting oxygen index (LOI); and a moderate-scale fire simulation test. The uncoated and coated foams were found to have excellent flammability and insulation characteristics, although smoke development was substantial.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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