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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 711-721 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the physical vapor deposition of compound semiconductor films that describes film growth from component molecular beams is presented. Constitutive relationships are used in the model to account for incomplete adsorption from the incident molecular beams, emission of adsorbed components into vacuum, and surface reactions of the elemental species. The model predicts film composition and growth rate as a function of incident fluxes and substrate temperature. It is applicable for important binary and ternary alloy semiconductors including the II-VI and III-V compounds over the range of deposition conditions yielding both stoichiometric and two-phase films. In this paper the model equations and the behavior predicted by the model are described for a number of material systems including (CdHg)Te, (CdZn)S, and CuInSe2.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 656-662 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Vacuum sublimation of cadmium sulfide for manufacture of thin film solar cells was analyzed. The sublimation unit consisted of a two chamber cylindrical source bottle having a rate control orifice and exit nozzle. Coupled heat and mass balance equations were solved using appropriate rate equations for flow in the free molecular-to-viscous transition regime. The model equations predicted that heat transfer has a significant effect on sublimation rate. Experiments were carried out over a range of temperatures with several rate control orifices and exit nozzles. Quantitative agreement between measured rates and those calculated from the model equations was obtained.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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