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Densities, Viscosities, Sound Speeds, and Excess Properties of Binary Mixtures of Methyl Methacrylate with Alkoxyethanols and 1-Alcohols at 298.15 and 308.15 K (2000)

Sastry, N. V. ; Patel, S. R.

Springer

International journal of thermophysics 21 (2000), S. 1153-1174

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ISSN: 1572-9567

Schlagwort(e): density ; methyl methacrylate +alcohol binary liquid mixtures ; molecular interactions ; relative association ; solvation number ; sound speed ; viscosity

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract The densities, viscosities, and sound speeds were measured for six binary mixtures of methyl methacrylate (MMA)+2-methoxyethanol (ME), +2-ethoxyethanol (EE), +2-butoxyethanol (BE), +1-butanol (1-BuOH), +1-pentanol (1-PeOH), and +1-heptanol (1-HtOH) at 298.15 and 308.15 K. The mixture viscosities were correlated by Grunberg–Nissan, McAllister, and Auslander equations. The sound speeds were predicted by using free length and collision factor theoretical formulations, and Junjie and Nomoto equations. The excess viscosities and excess isentropic compressibilities were also calculated. A qualitative analysis of both of these functions revealed that structure disruptions are more predominant in MMA+1-alcohol than in MMA+alkoxyethanols mixtures. The estimated relative associations are found to become less in MMA+alcohol mixtures than in pure alcohols. The solvation numbers derived from the isentropic compressibility of the mixtures, considering MMA as a solvent, showed that structure making interactions are also present in MMA + alkoxyethanols in addition to the structure disruptions.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1026402222130

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Digitale Medien

Internal mixing: A practical investigation of the influence of intermeshing rotor configuration and operating variables on mixing characteristics and flow dynamics (1987)

Freakley, P. K. ; Patel, S. R.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 27 (1987), S. 1358-1370

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ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: This paper deals with the measurement and interpretation of pressures and temperatures produced by the mixing of a rubber compound in the chamber of an internal mixer equipped with interlocking rotors. Pressure transducers and infrared/fiber optic temperature sensors were sited flush with the inner surface of the mixing chamber of a Francis Shaw KO Intermix of 2 L chamber volume. The variation of pressure with transducer position In the chamber wall and with rotor position was measured for selected fill factors and rotor speeds at “equilibrium” conditions (quasi-static power requirement for the mixer) and at intervals during a complete mixing cycle. Two rotor designs were studied. Interpretation of the results was carried out with reference to biconical rotor rheometer measurements on the mixed rubber compounds and by reference to four regimes of viscoelastic behavior identified for two-roll mill mixing. A basic flow analysis was carried out by use of the lubrication approximation in conjunction with an isothermal power-law model.

Zusätzliches Material: 22 Ill.