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  • Chemical Engineering  (401)
  • 1980-1984  (340)
  • 1955-1959  (61)
  • 1940-1944
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 411-417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the hydrogenation of α-methylstyrene by means of a suspended palladium-alumina catalyst in a stirred reactor the mass transfer of hydrogen through the liquid is the rate-controlling step and the resistance to chemical reaction at the catalyst surface is negligible except at extremely rapid rates of stirring. This system therefore provides an excellent means of establishing the effects of operating variables and mechanical construction on mass transfer coefficients in liquids in stirred reactors. It is convenient to consider the total resistance to mass transfer as consisting of two separate resistaces: in the liquid adjoining the bubbles and in the liquid adjoining the suspended solid particles; thus R = Rb + Rs.A general equation was evaluated from experimental data based upon unit volume of liquid.
    Additional Material: 14 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 514-515 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 79-86 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of reaction between CO2 and lime is investigated in the range of 673 to 998 K with a view to examining the effects of product layer deposition and variations in the limestone calcination atmosphere. The reaction is initially rapid and chemically controlled and goes through a sudden transition to a much slower regime controlled by diffusion in the product CaCO3 layer. The magnitude of the estimated product layer diffusivity is in the range of 10-18 to 10-21 m2/s, the corresponding activation energy is 88.9 ± 3.7 kJ/mol below 688 K and 179.2 ± 7.0 kJ/mol above that temperature, suggestive of solid state diffusion. Plausible mechanisms are discussed.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 625-631 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mixed oxide system of copper and tin and the active single oxide, Cu2O, were compared for reducibility of the copper ion, relative number and type of active sites, and reaction kinetics. The enhanced selectivity of the mixed oxides may result from the formation of highly selective sites at the expense of less selective sites. The reducibility of the copper ion in the mixture is influenced by the oxidation state of the tin ion. The reactant and product reaction orders are the same for both catalysts but the mixed oxides are more sensitive to inhibition by water. The catalyst composition affects the energetics of the reaction over the copper-tin oxide catalysts.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 56-62 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rate studies are reported of the effect of rehydration-dehydration cycling on the vapor hydration behavior of solid K2CO3. Isothermal rate data were obtained at different temperatures and water vapor pressures for the reaction of narrowlysized anhydrous particles. Effects of different particle preparation histories on the rehydration rate were investigated and correlations of rate with particle pore structure explored. Rehydration rates of dehydrated K2CO3·3/2H2O were found to depend on the conditions of the prior dehydration. Rehydration is comparatively very slow at relative pressures below P/Peq ≃ 1.5; rates increase linearly with pressure above P/Peq ≃ 3. Hydration rates of K2CO3 particles obtained as anhydrous are substantially slower than those of identically-sized crystals produced by prior dehydration of K2CO3·3/2H2O; after one rehydration-dehydration cycle, rehydration rates are increased by as much as two orders of magnitude and this distinction between sources virtually disappears. Diffusional resistances based on calculated water vapor diffusivities are qualitatively consistent with the observed effects of cycling but do not by themselves account fully for the observations.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 849-853 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 967-973 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general equation is derived that predicts the evolution of pore volume distribution during isothermal gasification in the regime of kinetic control, starting from a given initial condition. The development takes into account pore enlargement as well as pore intersections. Equations are also derived for the special cases of (1) uniform pore size and (2) bimodal distribution. The results are used to interpret the experimental data of Tomkow et al. (1977) and Kawahata and Walker (1962).
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 465-471 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental plate efficiency and pressure drop data were obtained on the n-octane-toluene system in a 5 plate, 6 in. diam. column at atmospheric pressure. Hole sizes of 1/16, 1/8, and 3/16 in.; 5.68 and 12.5% free areas; weir heights of 1, 2, and 3 in.; and plate spacings of 6, 12, 18, and 24 in. were studied. Reflux ratios of one, two, four, five, ten, and total were utilized to determine the effect on efficiency.It was found that hole diameter, free area, plate spacing, and a wide range of reflux ratio had relatively small effect on efficiency and pressure drop; however weir height and lower reflux showed relatively larger effects on both variables.Efficiencies and pressure drops were lower than those predicted from published correlations particularly at low flow rates.
    Additional Material: 12 Ill.
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  • 9
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data correlations are presented for equilibrium adsorption of pure hydrocarbon vapors and their mixtures. The systems represented are C1 to C4 hydrocarbons (olefins and paraffins) on gas-adsorbent grades of activated charcoal. The mixture data are limited to binary and ternary gas systems. The adsorption conditions represented among the correlated data cover ranges of 77° to 175°F. temperature and 0 to 100 lb./sq. in. gauge. With the use of empirical adsorption constants, a common correlation of specific adsorption capacity for the various hydrocarbons is presented; it applies for either pure components or their mixtures. A correlation is given also for adsorption relative volatilities. Approximate adsorption heats, a limited amount of high-temperature steam adsorption data, and sample calculations on applications of the correlations are included. The prediction methods are recommended for adsorption conditions up to 250°F. and 250 lb/sq. in. gauge for the particular systems studied.
    Additional Material: 7 Ill.
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  • 10
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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