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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1338-1348 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical model was developed to predict the heat and mass transfer phenomena in porous materials. A water-filled sandstone was heated in a convective oven and its water loss rates and temperature profiles were compared with theoretical results. In addition to local temperatures, moisture content, gas densities and pressure, this model also predicts the fluid flow pattern in the heated sample.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 365-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The approximate equations of Hassler and Brunner and of van Domselaar are often used to deduce the capillary pressure curve of a porous medium from centrifuge data. The use of these equations restricts the centrifuge method to short samples. Also, these equations require differentiation of data. We report here methods to determine the capillary pressure curve by the midpoint and least-squares solution of the fundamental equation, relating the average saturation S1 of liquid in the porous medium to the capillary pressure Pc1 at the end of the sample nearest the axis of rotation. The methods do not require differentiation of data and are not restricted to short samples. We introduce and evaluate an approximation based on an exact result derived by Rajan. This new approximation requires the same inputs as do the Hassler-Brunner and the van Domselaar approximations, but it is accurate over a wider range of sample sizes. In addition, an approximate solution which can be used to estimate capillary pressure curves for long cores is developed.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 842-848 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Our previous theoretical model was extended to predict the heat and mass transfer phenomena in microwave-heated porous materials. A water-filled sandstone was heated in microwaves and its drying rates and temperature profiles were measured. Predictions agree well with observations. Besides moisture loss rates and temperature profiles, the model also predicts local moisture content, gas densities, and pressure. These latter quantities were not measured in our work, but are of interest since they reveal the basic mechanisms of heat and mass transfer in internally heated porous media.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 123-129 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A light-extinction principle was used to measure the fall speeds of the interfaces that develop during gravity sedimentation of monodisperse, bidisperse, and tridisperse suspensions of noncolloidal particles with small particle Reynolds numbers in the semidilute total particle volume fraction range 0.0003 ≤ c0 ≤ 0.15. For monodisperse suspensions, the hindered settling velocity of the interface at the top of the suspension was found to be well represented by the correlation of Richardson and Zaki, provided that the isolated particle fall speed was chosen by linear extrapolation of the data to c0 = 0, with 90% confidence intervals on the exponent of n = 5.0 ± 0.1. For dilute monodisperse, bidisperse, and tridisperse suspensions, the hindered settling velocities of the interfaces showed agreement within experimental uncertainty with the theory of Batchelor, which predicts that the settling velocity decreases linearly with increasing particle concentration and which is based upon pairwise particle interactions.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1178-1186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gradient theory of equilibrium fluid microstructures is extended to nonequilibrium isothermal processes. The theory is applied to steady diffusion across liquid-liquid interfaces. It is shown that local equilibrium across a fluid-fluid interface is maintained even in the presence of very high diffusion fluxes and that the concept of an interface acting as an applied potential energy for a diffusing species is of limited utility. The theory is suited for practical, semiempirical calculations of structure, stress, and isothermal transport in systems containing interfaces.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 470-479 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Complete adiabatic fixed-bed adsorption cycles with adsorption, heating, and cooling steps are analyzed using simple wave theory. Solutions consist of simple waves, shocks, combined waves, and wave interactions with patterns established by a mapping between hodograph and physical planes. The system considered is benzene adsorbed on activated carbon with nitrogen as the carrier gas.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1310-1320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two light-scattering techniques have been applied to study the kinetics of droplet evaporation and attendant interfacial phenomena. The first technique, which is particularly useful for noisy data, utilizes the fast Fourier transform of phase function data (intensity vs. scattering angle) to obtain the size by comparing the phase function with Lorenz-Mie theory. The second method applies optical resonance measurements to obtain very precise measurements of size and/or refractive index as functions of time. The techniques have been used to measure the slow evaporation of multicomponent and single-component organic microdroplets, rapid evaporation of water droplets, and rapid evaporation of droplets of aqueous solutions and surfactant solutions. The experiments were performed in an electrodynamic balance, which was used to suspend single microdroplets in a polarized laser beam. Rapid evaporation rate data yield information on the surface temperature, and data for surfactant solution evaporation show that insoluble monolayer formation at the microdroplet surface reduces the evaporation rate by a factor of 200. In addition, it is shown that droplet explosion due to surface charge effects can occur well below the Rayleigh limit of charge.
    Additional Material: 14 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 175-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1116-1124 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model that describes fractionation with condensation and evaporation in a plate-fin device has been formulated. It is capable of evaluating profiles of composition, temperature, and flow rate for both liquid and vapor streams in an extended surface device. The device may be adiabatic or nonadiabatic and the surface may be incompletely wetted. Compared to experimental measurements, the model predictions showed ± 1 number of transfer unit deviation along the length of the device. The predictions of the top and bottom flow rate ratio showed a 5-10% deviation for adiabatic and condensation runs and a 25% deviation for evaporation runs.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1403-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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