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  • 1
    Electronic Resource
    Electronic Resource
    Theory of hydrogen bonding in supercritical fluids (1992)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1243-1253 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The degree of hydrogen bonding and macroscopic thermodynamic properties for pure and mixed fluids are predicted with the hydrogen bonding lattice fluid (LFHB) equation of state over a wide range in density encompassing the gas, liquid and supercritical states. The model is successful for molecules forming complex self-associated networks, in this case pure methanol, ethanol, and water, and the mixture 1-hexanol-SF6. In supercritical water, significant hydrogen bonding is still present despite all the thermal energy and is highly pressure- and temperature-dependent. A fundamental description of pressure and temperature effects on hydrogen bonding is presented for a well-defined case, the formation of a complex between a donor and acceptor in an inert solvent, where no self-association is present. The partial molar enthalpy and volume change on complexation both become pronounced near the critical point, where the density is highly variable with temperature and pressure.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690380811
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  • 2
    Electronic Resource
    Electronic Resource
    Compatibility between PVC and plasticizer blends and its relation with processing (1992)
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 14 (1992), S. 74-77 
    Details
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The compatibility of suspension PVC with various plasticizer blends was determined by means of calculated compatibility predictors, such as solubility parameters and polarity parameters, as well as actual measurements of compatibility. Then, with a torque rheometer, the temperature at the fusion peak was obtained for various PVC/plasticizer blend compositions. Finally, empirical equations were derived to relate compatibility parameters with the temperature at the fusion peak, predicting the effect of plasticizer blend on processability.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/vnl.730140206
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  • 3
    Electronic Resource
    Electronic Resource
    Chemically crosslinked poly(vinyl chloride) (1991)
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 13 (1991), S. 184-186 
    Details
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of mixing time, temperature, and thermal treatment on mechanical properties of crosslinked PVC is investigated. The tensile properties and gel content of crosslinked and uncrosslinked PVC molded samples are evaluated. The cured samples exhibited higher tensile strength and thermal stability than unmodified PVC.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/vnl.730130404
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  • 4
    Electronic Resource
    Electronic Resource
    The fusion characteristics of PVC-plasticizer mixtures (1991)
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 13 (1991), S. 160-164 
    Details
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dry blends of a PVC resin with various plasticizer mixtures were processed at different temperatures to produce samples of different degrees of fusion. The ease of fusion increased with decreasing the solid-gel transition temperature (Tm) of the plasticizer mixture. Nevertheless. Tm was not necessarily a linear function of the individual concentration of plasticizers in the mixture. Therefore, the ease of fusion showed in some cases an optimum at a given concentration of the plasticizer mixture.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/vnl.730130311
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  • 5
    Electronic Resource
    Electronic Resource
    Effect of talc surface treatment on the mechanical properties of composites based on PP/LDPE blend matrices (1991)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 245-252 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study has been made of property optimization of a composite based on low density polyethylene and polypropylene (PP) blend matrices with talc modified by a titanate coupling agent. Analysis shows that the flexural properties improve with increasing content of both talc and polypropylene. However, the tensile moduli show a different behavior. Tensile strength is hardly affected by the filler content at PP percentages in the matrix above 50 percent. The surface modified talc gives rise to higher mechanical properties than the unmodified talc. This improvement is more noticeable as talc and PP percentages in the composite is increased. Scanning electron microscopy has shown the effect of the coupling agent at the filler/polymer matrix interphase and the greater affinity between talc and polypropylene.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760310407
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  • 6
    Electronic Resource
    Electronic Resource
    Influence of reprocessing on the mechanical properties of a commercial polysulfone/polycarbonate blend (1992)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 861-867 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Commercial polysulfone/polycarbonate (PSU/PC) polymer blends were reprocessed up to five times to determine the influence that reprocessing has on their structure and physical properties. All the high strain properties, mainly ductility, significantly decreased under harsh processing conditions, such as five cycles at 320°C. The results of reprocessing the blends at 320°C have been compared with results at a lower temperature and also with those of the separate components with the aim of clarifying the origin of the degradation. These results plus Fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis, and melt flow index measurements (MFI) indicate that the presence of the two polymers together clearly decreases the resistance to degradation of each component. Moreover, degradation under the stated conditions is mainly thermal and does not change the chemical nature of the blends. However, a clear decrease in molecular weight was observed both by viscosimetry and MFI measurements as was a shift to higher temperatures of the low temperature secondary transition of both PC and PSU. Both molecular weight and secondary transition changes usually deteriorate mechanical properties but not in the degree observed here. This probably means that the fine and difficult-to-observe structure of the blend has also changed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760321305
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