Publication Date:
2012-09-26
Description:
A dicobaloxime in which monomeric Co(III) units are linked by an octamethylene bis(glyoxime) catalyzes the reduction of protons from p-toluenesulfonic acid as evidenced by electrocatalytic waves at -0.4 V vs. the saturated calomel electrode (SCE) in acetonitrile solutions. Rates of hydrogen evolution were determined from catalytic current peak heights (kapp = 1100 ± 70 M-1 s-1). Electrochemical...
Keywords:
Chemical Approaches to Artificial Photosynthesis: Solar Fuels Special Feature
Print ISSN:
0027-8424
Electronic ISSN:
1091-6490
Topics:
Biology
,
Medicine
,
Natural Sciences in General
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