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  • Center for Marine Environmental Sciences; MARUM  (4)
  • Chromans
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  • 1
    ISSN: 1573-1421
    Keywords: Chromans ; homohopenes ; isoprenoid thiolanes ; isoprenoid thiophenes ; methylated MTTC ; Nördlinger Ries ; tocopherols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Distributions of alkylated chromans and C20 isoprenoid thiophenes were investigated in four organic-matter- and sulfur-rich black shales of Miocene age deposited in the ancient crater lake of the Nördlinger Ries (southern Germany), a meteorite impact crater. Paleosalinity parameters based on these compound classes generally confirm sedimentological evidence of increased salinity over certain periods of the lake's history, but the data from both groups of compounds are not consistent. Diagenetically related molecular constituents were therefore studied to estimate the sensitivity of these parameters. The influence of thiolanes on the isoprenoid thiophene parameter was found to be low, whereas too little is known at present about the origin and diagenetic fate of alkylated chromans to conclude definitely that an alkylated chroman paleosalinity parameter can reliably be applied to a wide range of depositional settings.
    Type of Medium: Electronic Resource
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  • 2
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    PANGAEA
    In:  Supplement to: Vogts, Angela; Badewien, Tanja; Rullkötter, Jürgen; Schefuß, Enno (2016): Near-constant apparent hydrogen isotope fractionation between leaf wax n-alkanes and precipitation in tropical regions: Evidence from a marine sediment transect off SW Africa. Organic Geochemistry, 96, 18-27, https://doi.org/10.1016/j.orggeochem.2016.03.003
    Publication Date: 2023-03-03
    Description: A transect of marine surface sediment samples from 1° N to 28° S off southwest Africa was analysed to verify the application of hydrogen isotope compositions of terrestrial plant-wax n-alkanes preserved in ocean sediments as a proxy for continental hydrological conditions. Conditions on the adjacent continent range from humid evergreen forests to deciduous forests, wood- and shrub land and further to arid grasslands and deserts. The hydrogen isotope values for the dominant n-alkane homologues (C29, C31 and C33) vary from -123 per mil to -141 per mil VSMOW and correlate with the modelled hydrogen isotope composition of mean annual and growing season precipitation of postulated continental source areas (r up to 0.8, p 〈 0.01). The apparent hydrogen isotope fractionation between alkanes and mean annual precipitation is remarkably uniform (-109 per mil on average, Sigma 〈= 5 per mil, n = 27). Potentially, effects of aridity on the apparent hydrogen isotope fractionation are concealed by the contribution of different plants (C3 dicotyledons vs C4 grasses). Thus, isotope ratios of leaf wax n-alkanes preserved in ocean margin sediments in these and similar tropical regions may be directly converted to dD ratios of ancient precipitation by employing a constant hydrogen isotope fractionation.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 7 datasets
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  • 3
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    PANGAEA
    In:  Supplement to: Vogts, Angela; Schefuß, Enno; Badewien, Tanja; Rullkötter, Jürgen (2012): n-Alkane parameters from a deep sea sediment transect off Southwest Africa reflect continental vegetation and climate conditions. Organic Geochemistry, 47, 109-119, https://doi.org/10.1016/j.orggeochem.2012.03.011
    Publication Date: 2023-03-03
    Description: An isobathic transect of marine surface sediments from 1°N to 28°S off southwest Africa was used to further evaluate the potential of the chain length distribution and carbon stable isotope composition of higher plant n-alkanes as proxies for continental vegetation and climate conditions. We found a strong increase in the n-C29-33 weighted mean average d13C values from -33 per mil near the equator to around -26 per mil further south. Additionally, C25-35n-alkanes reveal a southward trend of increasing average chain length from 30.0 to 30.5. The data reflect the changing contribution of plants employing different photosynthetic pathways (C3 and C4) and/or being differently influenced by the environmental conditions of their habitat. The C4 plant proportions calculated from the data (ca. 20% for rivers draining the rainforest, to ca. 70% at higher latitude) correspond to the C4 plant abundance in continental catchment areas postulated by considering prevailing wind systems and river outflows. Furthermore, the C4 plant contribution to the sediments correlates with the mean annual precipitation and aridity at selected continental locations in the postulated catchment areas, suggesting that the C4 plant fraction in marine sediments can be used to assess these environmental parameters.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 7 datasets
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  • 4
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    PANGAEA
    In:  Supplement to: Schefuß, Enno; Eglinton, Timothy Ian; Spencer-Jones, Charlotte L; Rullkötter, Jürgen; De Pol-Holz, Ricardo; Talbot, Helen M; Grootes, Pieter Meiert; Schneider, Ralph R (2016): Hydrologic control of carbon cycling and aged carbon discharge in the Congo River basin. Nature Geoscience, 9(9), 687-690, https://doi.org/10.1038/ngeo2778
    Publication Date: 2023-03-11
    Description: The age of organic material discharged by rivers provides information about its sources and carbon cycling processes within watersheds. While elevated ages in fluvially-transported organic matter are usually explained by erosion of soils and sediments, it is commonly assumed that mainly young organic material is discharged from flat tropical watersheds due to their extensive plant cover and high carbon turnover. Here we present compound-specific radiocarbon data of terrigenous organic fractions from a sedimentary archive offshore the Congo River in conjunction with molecular markers for methane-producing land cover reflecting wetland extent in the watershed. We find that the Congo River has been discharging aged organic matter for several thousand years with increasing ages from the mid- to the Late Holocene. This suggests that aged organic matter in modern samples is concealed by radiocarbon from nuclear weapons testing. By comparison to indicators for past rainfall changes we detect a systematic control of organic matter sequestration and release by continental hydrology mediating temporary carbon storage in wetlands. As aridification also leads to exposure and rapid remineralization of large amounts of previously stored labile organic matter we infer that this process may cause a profound direct climate feedback currently underestimated in carbon cycle assessments.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 5
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    PANGAEA
    In:  Supplement to: Badewien, Tanja; Vogts, Angela; Dupont, Lydie M; Rullkötter, Jürgen (2015): Influence of Late Pleistocene and Holocene climate on vegetation distributions in southwest Africa elucidated from sedimentary n-alkanes - Differences between 12°S and 20°S. Quaternary Science Reviews, 125, 160-171, https://doi.org/10.1016/j.quascirev.2015.08.004
    Publication Date: 2023-05-12
    Description: Global and local climatic forcing, e.g. concentration of atmospheric CO2 or insolation, influence the distribution of C3 and C4 plants in southwest Africa. C4 plants dominate in more arid and warmer areas and are favoured by lower pCO2 levels. Several studies have assessed past and present continental vegetation by the analysis of terrestrial n-alkanes in near-coastal deep sea sediments using single samples or a small number of samples from a given climatic stage. The objectives of this study were to evaluate vegetation changes in southwest Africa with regard to climatic changes during the Late Pleistocene and the Holocene and to elucidate the potential of single sample simplifications. We analysed two sediment cores at high resolution, altogether ca. 240 samples, from the Southeast Atlantic Ocean (20°S and 12°S) covering the time spans of 18 to 1 ka and 56 to 2 ka, respectively. Our results for 20°S showed marginally decreasing C4 plant domination (of ca. 5%) during deglaciation based on average chain length (ACL27-33 values) and carbon isotopic composition of the C31 and C33 n-alkanes. Values for single samples from 18 ka and the Holocene overlap and, thus, are not significantly representative of the climatic stages they derive from. In contrast, at 12°S the n-alkane parameters show a clear difference of plant type for the Late Pleistocene (C4 plant domination, 66% C4 on average) and the Holocene (C3 plant domination, 40% C4 on average). During deglaciation vegetation change highly correlates with the increase in pCO2 (r² = 0.91). Short-term climatic events such as Heinrich Stadials or Antarctic warming periods are not reflected by vegetation changes in the catchment area. Instead, smaller vegetation fluctuations during the Late Pleistocene occur in accordance with local variations of insolation.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 2 datasets
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