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  • Chemistry  (77)
  • Life and Medical Sciences  (24)
  • Cell & Developmental Biology  (22)
  • Wiley-Blackwell  (101)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Cell Motility and the Cytoskeleton 1 (1980), S. 73-97 
    ISSN: 0886-1544
    Keywords: nematodes ; muscle structure ; mutants ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: A search for new mutants with altered body-wall muscle cell structure has been undertaken in the nematode C elegans. One-hundred seventeen mutants were isolated after mutagenesis with ethyl methanesulfonate or ultraviolet light, enrichment by a motility-requiring test, and screening by polarized light microscopy; 102 of these mutants were in ten previously established genes, whereas 15 mutants permitted the identification of seven new complementation groups in C elegans. Two of the new genes map on linkage group I (unc-94 and unc-95) and four genes are sex linked (unc-96, unc-97, unc-98, and unc-99). One complementation group (unc-100) could not be mapped because of the special characteristics of its cohort mutants. Representative mutants of the mapped genes were examined by polarized light and electron microscopy. All of the mutants exhibit disruptions of the normal A and I band organization of thick and thin filaments. Several of the mutants produce collections of thin filament-like structures. In one of these cases, HE177 demonstrated collections of somewhat wider, intermediate-sized filaments as well, and the HE195 mutant produces paracrystalline aggregates of thin filaments amidst looser arrangements of similar structures. The mutants in newly identified genes, as well as the new mutants in previously established genetic loci, have promise as tools in the study of myofibrillar assembly and function. Among the 22 complementation groups associated with body-wall structure in C elegans, it is likely that some genes code for regulatory and morphogenetic functions in addition to the well-studied structural, contractile, and calcium-associated proteins in muscle.
    Additional Material: 15 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 1227-1234 
    ISSN: 0887-624X
    Keywords: polyanilines ; derivatives ; chemical synthesis ; oxidation state ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Syntheses of parent polyaniline and methyl, methoxy, and ethoxy ortho-substituted polyanilines were performed using the conventional chemical methodology and monitored using the new open-circuit-potential (Voc) profile technique. The intermediate pernigraniline oxidation state was identified and isolated at the Voc maximum (A) during the conventional chemical synthesis of poly(o-methoxyaniline) in the emeraldine oxidation state. The introduction of the substituent on the aniline ring leads to longer polymerization times and lower Voc values. Syntheses in the presence of two different monomers in solution were also investigated and showed preferential polymerization of the monomer with the lowest Voc potential. All polymers produced were characterized by elemental analysis, gel permeation chromatography, UV-VIS spectroscopy, and cyclic voltammetry. The influence of the substituent on the Voc profile and on the polymer characteristics are rationalized in terms of steric and electronic effects. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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  • 3
    ISSN: 0886-1544
    Keywords: erythroid spectrin ; non-erythroid spectrin ; Z-line ; membrane ; neuromuscular junction ; developmental changes ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: We describe multiple human cardiac and skeletal muscle spectrin isoforms. Cardiac muscle expresses five erythroid α,β spectrin-reactive isoforms with estimated MR's of 280, 274, 270, 255, and 246 kD, respectively At least one nonerythroid α-spectrin of MR 284 kD is expressed in heart. While skeletal muscle shares the 280, 270, and 246 kD erythroid spectrins, it expresses an immunologically distinct 284 kD nonerythroid α-spectrin isoform. The 255 kD erythroid β-spectrin isoform is specific for cardiac tissue. By immunocytochemistry, both erythroid β- and nonerythroid α-spectrins are localized to costameres, the plasma membrane, and the neuromuscular junctional region.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 42 (1904), S. 341-352 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 5
    ISSN: 0959-8103
    Keywords: polyaniline ; pernigraniline oxidation state ; copolymer ; synthesis ; electrochemistry ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyaniline was electrochemically synthesized in the emeraldine oxidation state and then converted to the pernigraniline oxidation state by applying an electric potential under optimized conditions. The stability/reactivity of polyaniline in the pernigraniline oxidation state was evaluated in various aqueous media. The products of the reduction of the pernigraniline oxidation state by o-toluidine were analyzed by gel permeation chromatography, ultraviolet-visible and infrared spectroscopies, and cyclic voltammetry. The results are consistent with the synthesis of a diblock copolymer of polyaniline/poly(o-toluidine) and also of some poly(o-toluidine) homopolymer in the emeraldine oxidation state as a side product.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 375-375 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 1629-1646 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The purpose of the present work has been to produce knowledge as regards the rheological behavior of polymer matrix in nonwoven fibrous reinforcing structures for composites. The results are expected to contribute toward a better understanding of flow mechanisms in fibrous systems in order to develop better techniques for fabricating elastomer-based composites. Theoretical and experimental analyses have been made of interactions between the structural parameters of the fibrous mats and the flow characteristics of the matrix with systematically varied material and process parameters. In nonwoven mats with fibers laid lengthwise, the flow rate along the fiber direction was found to be significantly higher than the flow rate crosswise to the fiber direction. Nonwoven mats with multidirectionally laid fibers exhibited a practically radial flow front pattern. Nonwoven mats made of coarser fibers showed greater matrix polymer flow rate as compared with finer fibers. The matrix flow distance was proportional to the logarithm of injection time. The decrease of pressure in the mold cavity was linearly proportional to the matrix flow distance. The dependence of permeability on the level of compression of the fibrous structure is in agreement with the results published by other workers. © 1994 John Wiley & Sons, Inc.
    Additional Material: 21 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 1693-1704 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new type of mold was developed and tested for structural reaction injection molding (SRIM) of elastomer composites having polymer matrices made from a mixture of two components. These mixtures had short pot lives and relatively high viscosity. Channel systems for polymer feeding and vacuum application were investigated. The mold cavity was provided with up to 24 polymer feeding holes and 38 vacuuming holes. The cavity and channels were made from transparent materials that allowed easy observation and video recording of the polymer matrix flow. In addition, some design parameters were studied such as channel layout. Investigations were carried out on the mechanism of polymer matrix flow and fiber breakage during the formation of fiber-reinforced composites made of non-woven fiber reinforcement structures with considerably longer fiber lengths than reported earlier. Other studies included determination of the effects of fiber type, fiber dimensions, and fiber/matrix v/v ratio on the matrix flow during impregnation. © 1992 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 57 (1995), S. 751-765 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of fiber type and fiber-surface properties on matrix flow behavior was investigated using structural reaction injection-molding (SRIM). The influence of fiber type, fiber-surface properties, and matrix type on strength properties in elastomeric composites reinforced with nonwoven fibrous structures was investigated using tensile tests on elastomer composite samples from SRIM and latex coagulation (LC) fabrication methods and the microbond strength method on individual fibers. The fibers used were PET, LLDPE, and p-aramid. Fibers were treated with epoxy, styrene, and isocyanate derivatives, which make the surface chemically reactive. Treatments were also made with NaOH and a copolymer of polyester and polyol ether, causing a change in the fiber surface energy. The matrix types were polyurethane elastomer and natural rubber. The results show that the surface treatments which produced a change in the surface energy influenced the flow rate of the matrix polymer during the composite fabrication process. The treatments resulted in chemically reactive fiber surfaces which improved the fiber-matrix bond strength without affecting the Young's modulus of the composite material. Good correlation was found between bond strength and surface energy including the dispersive component of surface energy in the case of polyurethane elastomer and surface-modified PET fibers. The age of the polyurethane matrix has a marked influence on the bond strength. The fiber volume fraction in composites has a strong influence on the Young's modulus of the elastomer composite. © 1995 John Wiley & Sons, Inc.
    Additional Material: 16 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 27-33 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Solid state rolling of semi-crystalline polymers is shown to be an effective method of producing high strength, high modulus tape at acceptable production rates. High density polyethylene tape was produced having a tensile strength exceeding 300 MPa and a tensile modulus of 8.7 GPa at production rates exceeding 8 m/min. A significant factor in producing highly oriented tape by the rolling process is roll temperature. Increasing the roll temperature from 25°C to 125°C not only increases the maximum extent of orientation achievable, but increases the mechanical properties at a given degree of thickness reduction. Internal frictional heat development limited the maximum thickness reduction ratio of polypropylene to 6.6:1. This reduction was reached by rolling at 150°C. The resultant tape had a tensile modulus of 5.1 GPa and a tensile strength of 300 MPa.
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