ISSN:
0570-0833
Keywords:
Trimethylphosphane complexes
;
Phosphane ligands
;
Homogeneous catalysis
;
Catalysis
;
Cobalt
;
Nickel
;
Iron
;
P ligands
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
One of the greatest achievements of organometallic chemistry in the last ten years has been the experimental proof that transition metal-to-carbon bonds are thermodynamically about as stable as those between main group elements and carbon. The present contribution demonstrates how simply constituted alkylnickel, -cobalt, and -iron complexes are obtained by means of a kinetic stabilization using suitable neutral ligands and what information these model compounds can provide with respect to the course of processes in homogeneous catalyses.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.198003621
Permalink
