ISSN:
0044-2313
Keywords:
Heteronuclear Metal Complexes
;
Metal - Metal-Bonds
;
Copper
;
Carbonylmanganate
;
Nitrosyl-carbonyl-ferrate
;
Carbonylcobaltate
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Heteronuclear Coordination Compounds with Metal - Metal Bonds. VIII. New Heterodinuclear Complexes with Bonds between Copper(I) and Manganese(-I), Iron(-I), or Cobalt(-I)[(en)Cu—Mn(CO)5] (1a), [(dien)Cu—Mn(CO)5] (1b), [(en)Cu—Fe(CO)3(NO)] (2a), [(dien)Cu—Fe(CO)3(NO)] (2b), [(en)Cu—Co(CO)4] (3a), and [(dien)Cu—Co(CO)4] (3b) are new heterobinuclear metal - metal bonded complexes. The geometry of the [Mn(CO)5]-, [Fe(CO)3(NO)]-, and [Co(CO)4]- ions is distorted only to a less extend in accord with a heteropolar bond to copper.
Notes:
[(en)Cu—Mn(CO)5] (1a), [(dien)Cu—Mn(CO)5] (1b), [(en)Cu—Fe(CO)3(NO)] (2a), [(dien)Cu—Fe(CO)3(NO)] (2b), [(en)Cu—Co(CO)4] (3a) und [(dien)Cu—Co(CO)4] (3b) sind neue heteronukleare Zweikernkomplexe mit Metall - Metall-Bindungen, in denen die Geometrie der [Mn(CO)5]--, [Fe(CO)3(NO)]-- und [Co(CO)4]--Ionen durch die Bindung an Kupfer im Sinne einer heteropolaren Wechselwirkung nur wenig verzerrt wird.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210219
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