ISSN:
0935-6304
Keywords:
Capillary supercritical fluid chromatography
;
Inductively coupled plasma-mass spectrometry
;
On-line SFC-ICPMS
;
Organometallic compounds
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Supercritical fluid chromatography with inductively coupled plasma-mass spectrometric detection is a new and useful technique for the analysis of organometallic compounds. An interface has been developed for coupling these techniques. The interface is compact, easy to assembel, and causes minimal disruption to either instrument. A series of organotin, organoarsenic, and organorion compounds has been used to evaluate the interface and ICPMS as a detector for SFC. The effect of analyte concentration and restrictor temperature on peak intensity has been investigated and the effect of the mobile phase on the plasma has also been studied to assess background interference from changes in the plasma.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240180108
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