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  • 1
    Publication Date: 2019-06-28
    Description: Thermal and rheological properties of a commercial thermoplastic polyimide, NEW-TPI (trademark), were characterized. The as-received material possesses initially a transient crystallite form with a bimodal distribution in peak melting temperatures. After the melting of the initial crystallite structure, the sample can be recrystallized by various thermal treatments. A bimodal or single modal melting peak distribution is formed for annealing temperatures below or above 360 C, respectively. The recrystallized crystallinities are all transient in nature. The polymers are unable to be recrystallized after being subjected to elevated temperature annealing above 450 C. The recrystallization mechanism was postulated, and a simple kinetics model was found to describe the behavior rather satisfactory under the conditions of prolonged thermal annealing. Rheological measurements made in the linear viscoelastic range support the evidence observed in the thermal analysis. Furthermore, the measurements sustain the manufacturer's recommended processing window of 400 to 420 C for this material.
    Keywords: COMPOSITE MATERIALS
    Type: NASA-CR-187445 , NAS 1.26:187445
    Format: application/pdf
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  • 2
    Publication Date: 2019-06-28
    Description: This final technical report contains three parts: Part 1 deals with the 2-D shell theory and its element formulation and applications. Part 2 deals with the 3-D degenerated element. These two parts constitute the two major tasks that were completed under the grant. Another related topic that was initiated during the present investigation is the development of a nonlinear material model. This topic is briefly discussed in Part 3. To make each part self-contained, conclusions and references are included in each part. In the interest of brevity, the discussions presented are relatively brief. The details and additional topics are described in the references cited.
    Keywords: COMPOSITE MATERIALS
    Type: NASA-CR-191055 , E-7533 , NAS 1.26:191055
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  • 3
    Publication Date: 2019-06-28
    Description: A probabilistic finite element analysis procedure for laminated composite shells has been developed. A total Lagrangian finite element formulation, employing a degenerated 3-D laminated composite shell with the full Green-Lagrange strains and first-order shear deformable kinematics, forms the modeling foundation. The first-order second-moment technique for probabilistic finite element analysis of random fields is employed and results are presented in the form of mean and variance of the structural response. The effects of material nonlinearity are included through the use of a rate-independent anisotropic plasticity formulation with the macroscopic point of view. Both ply-level and micromechanics-level random variables can be selected, the latter by means of the Aboudi micromechanics model. A number of sample problems are solved to verify the accuracy of the procedures developed and to quantify the variability of certain material type/structure combinations. Experimental data is compared in many cases, and the Monte Carlo simulation method is used to check the probabilistic results. In general, the procedure is quite effective in modeling the mean and variance response of the linear and nonlinear behavior of laminated composite shells.
    Keywords: COMPOSITE MATERIALS
    Type: NASA-CR-191069 , E-7579 , NAS 1.26:191069
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  • 4
    Publication Date: 2019-06-28
    Description: A low pressure processor was developed for preparing a well-consolidated polyimide composite laminate. Prepreg plies were formed from unidirectional fibers and a polyamic acid resin solution. Molding stops were placed at the sides of a matched metal die mold. The prepreg plies were cut shorter than the length of the mold in the in-plane lateral direction and were stacked between the molding stops to a height which was higher than the molding stops. The plies were then compressed to the height of the stops and heated to allow the volatiles to escape and to start the imidization reaction. After removing the stops from the mold, the heat was increased and 0 - 500 psi was applied to complete the imidization reaction. The heat and pressure were further increased to form a consolidated polyimide composite laminate.
    Keywords: COMPOSITE MATERIALS
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  • 5
    Publication Date: 2019-07-12
    Description: The micromechanical constitutive theory is used to examine the nonlinear behavior of continuous-fiber-reinforced metal-matrix composite structures. Effective lamina constitutive relations based on the Abouli micromechanics theory are presented. The inelastic matrix behavior is modeled by the unified viscoplasticity theory of Bodner and Partom. The laminate constitutive relations are incorporated into a first-order deformation plate theory. The resulting boundary value problem is solved by utilizing the finite element method. Attention is also given to computational aspects of the numerical solution, including the temporal integration of the inelastic strains and the spatial integration of bending moments. Numerical results the nonlinear response of metal matrix composites subjected to extensional and bending loads are presented.
    Keywords: COMPOSITE MATERIALS
    Type: Computers and Structures (ISSN 0045-7949); 40; 6 19
    Format: text
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  • 6
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: Thermal and rheological properties of a commercial thermoplastic polyimide, NEW-TPI, were characterized. The as-received material possesses initially a transient crystallite form with a bimodal distribution in peak melting temperatures. After the meltings of the initial crystallite structures, the sample can be recrystallized by various thermal treatments. A bimodal or single-modal melting peak distribution is formed for annealing temperatures below or above 360 C, respectively. The recrystallized crystallinities are all transient in nature. The polymers are unable to be recrystallized after being subjected to elevated temperature annealing above 450 C. The recrystallization mechanism was postulated, and a simple kinetics model was found to describe the behavior satisfactorily under conditions of prolonged thermal annealing.
    Keywords: COMPOSITE MATERIALS
    Type: SAMPE Quarterly (ISSN 0036-0821); 22; 38-46
    Format: text
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