ISSN:
0009-2940
Keywords:
Ruthenium complexes
;
Stibane complexes
;
Dihydrogen complexes
;
Butadiene complex
;
π-Allyl complex
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The hydridoruthenium(II) complexes [RuHCl(H2)(SbiPr3)3] (2) and [RuH2(H2(SbiPr3)3] (3), containing dihydrogen as ligand, were prepared from [RuCl2(C8H12)]n (1) as the starting material. Compound 3 reacts with CO by displacement of H2 to yield [RuH2(CO)(SbiPr3)3] (4) and with C2H4 to give both [RuH2(C2H4)2(SbiPr3)2] (5) and [RuH2(C2H4)(SbiPr3)3] (6), the latter as the more stable and isolable product. Treatment of 3 with propene leads to the formation of [Ru(η3-C3H5)2] (7) while the reaction of 3 with butadiene affords the pentacoordinated ruthenium(0) compound [Ru(η4-C4H6)2(SbiPr3)] (8). The molecular structure of the bis-(allyl) complex 7 was determined by X-ray crystallography.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961291008
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