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Sannamycin-Type Aminoglycoside Antibiotics - Efficient Syntheses - Biological Activity (1998)

Erbeck, Silke ; Liang, Xifu ; Hunkler, Dieter ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 1935-1948

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ISSN: 1434-193X

Keywords: Sannamycin-type antibiotics ; Aminoglycoside syntheses ; Glycosylation ; Biological activity ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Shorter and more efficient routes to 6′-des(N-methyl)sannamycin A (1) and its 2′-epi analog 2 have been elaborated with the proven sannamine-type acceptor 10 and the glycosyl donors 5-8 featuring novel protecting patterns. With glycal 9 as glycosyl donor (and 10) an expedient access to 2′-desamino- (3) and 2′-desamino-2′-epi-hydroxysannamycin A (4) has been opened. For 4 a modest antibacterial activity was found, while 3 was inactive.

Type of Medium: Electronic Resource

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