ISSN:
1434-4475
Keywords:
Binuclear compounds
;
EPR-Spectra simulation
;
Hydrodynamic radii
;
15N-Labeled compounds
;
Reorientation correlation time
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The EPR spectra of Cu(II)-complexes of substituted 4-R-phenyl-aminomethylene-Δ2-pyrazolinones-(5) [R = N(CH3)2,p-OCH3, H,p-Cl,p-NO2] were obtained using polycrystalline samples and solutions. The spin-Hamiltonian parameters $$\tilde g, \tilde A, \tilde D$$ and theDebye radii have been determined. In toluene mononuclear and binuclear species can be detected. The Cu-Cu-distance has been estimated to be 0.43 nm.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00799238
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