ISSN:
0009-2940
Keywords:
Benzoquinones, substituted
;
Cyclic voltammetry
;
Cathodic dioxygen reduction, mediated
;
Anodic Wacker oxidation, mediated
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydroxy- (1a-3a) and hydroxyalkyl-substituted benzoquinones (6a-8a, 27a), suited to be immobilized by esterification with polyacrylic acid, are prepared. Their cathodic reduction potential Ep,c (1) correlates linearly with their substituent constant. The cathodic reduction of dioxygen and the palladium(II)-catalyzed anodic oxidation of alkenes are mediated by the benzoquinones 7b, 8b and 27b, respectively.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270513
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