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  • Adsorption  (1)
  • Ballast  (1)
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Marine Chemistry 170 (2015): 49-60, doi:10.1016/j.marchem.2015.01.006.
    Description: The natural radionuclides 231Pa and 230Th are incorporated into the marine sediment record by scavenging, or adsorption to various particle types, via chemical reactions that are not fully understood. Because these isotopes have potential value in tracing several oceanographic processes, we investigate the nature of scavenging using trans-Atlantic measurements of dissolved (〈0.45 μm) and particulate (0.8-51 μm) 231Pa and 230Th, together with major particle composition. We find widespread impact of intense scavenging by authigenic Fe/Mn (hydr)oxides, in the form of hydrothermal particles emanating from the Mid-Atlantic ridge and particles resuspended from reducing conditions near the seafloor off the coast of West Africa. Biogenic opal was not found to be a significant scavenging phase for either element in this sample set, essentially because of its low abundance and small dynamic range at the studied sites. Distribution coefficients in shallow (〈 200 m) depths are anomalously low which suggests either the unexpected result of a low scavenging intensity for organic matter or that, in water masses containing abundant organic-rich particles, a greater percentage of radionuclides exist in the colloidal or complexed phase. In addition to particle concentration, the oceanic distribution of particle types likely plays a significant role in the ultimate distribution of sedimentary 230Th and 231Pa.
    Description: Cruise management for GA03 was funded by the U. S. National Science Foundation to W. Jenkins (OCE-0926423), E. Boyle (OCE-0926204), and G. Cutter (OCE-0926092). Radionuclide studies were supported by NSF (OCE-0927064 to LDEO, OCE-0926860 to WHOI, OCE- 0927757 to URI, and OCE-0927754 to UMN). Additional support came from the European Research Council (278705) to LFR and the Ford Foundation Predoctoral Fellowship to SMV. Particle studies were supported by NSF OCE-0963026 to PJL.
    Keywords: GEOTRACES ; Suspended particulate matter ; Adsorption ; Radioactive tracers ; Trace elements
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part II: Topical Studies in Oceanography 116 (2015): 303-320, doi:10.1016/j.dsr2.2014.11.020.
    Description: The concentration and the major phase composition (particulate organic matter, CaCO3, opal, lithogenic matter, and iron and manganese oxyhydroxides) of marine particles is thought to determine the scavenging removal of particle-reactive TEIs. Particles are also the vector for transferring carbon from the atmosphere to the deep ocean via the biological carbon pump, and their composition may determine the efficiency and strength of this transfer. Here, we present the first full ocean depth section of size-fractionated (1–51 µm, 〉51 µm) suspended particulate matter (SPM) concentration and major phase composition from the US GEOTRACES North Atlantic Zonal Transect between Woods Hole, MA and Lisbon, Portugal conducted in 2010 and 2011. Several major particle features are notable in the section: intense benthic nepheloid layers were observed in the western North American margin with concentrations of SPM of up to 1648 µg/L, two to three orders of magnitude higher than surrounding waters, that were dominated by lithogenic material. A more moderate benthic nepheloid layer was also observed in the eastern Mauritanian margin (44 µg/L) that had a lower lithogenic content and, notably, significant concentrations of iron and manganese oxyhydroxides (2.5% each). An intermediate nepheloid layer reaching 102 µg/L, an order of magnitude above surrounding waters, was observed associated with the Mediterranean Outflow. Finally, there was a factor of two enhancement in SPM at the TAG hydrothermal plume due almost entirely to the addition of iron oxyhydroxides from the hydrothermal vent. We observe correlations between POC and CaCO3 in large (〉51 µm) particles in the upper 2000 m, but not deeper than 2000 m, and no correlations between POC and CaCO3 at any depth in small (〈51 µm) particles. There were also no correlations between POC and lithogenic material in large particles. Overall, there were very large uncertainties associated with all regression coefficients for mineral ballast (“carrying coefficients”), suggesting that mineral ballast was not a strong predictor for POC in this section.
    Description: US and International GEOTRACES Offices (NSF OCE-0850963 and OCE-1129603)
    Keywords: Particles ; SPM ; CaCO3 ; Opal ; Biogenic silica ; POC ; Ballast ; Dust ; Lithogenic material
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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