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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 625-627 
    ISSN: 1573-4846
    Keywords: composite materials ; sol-gel-process ; methacrylate copolymers ; dynamic-mechanical-analysis ; electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Sol gel derived composite materials were prepared from methacryloxypropyltrimethoxysilane (MPTS) and tetraethyleneoxidedimethacrylate (TEGDMA). The amount of MPTS in the composites was varied from 0 to 50 mole%. MPTS was prehydrolyzed at room temperature with 0,1 mole/l HCl/H2O. After complete removal of solvent calculated amounts of TEGDMA were added to the reaction mixture of the prehydrolyzed MPTS. Thermically initiated free radical copolymerization of the methacrylate endgroups was performed in the resulting mixture under nitrogen atmosphere using azobisisobutyronitril (AIBN) as initiator. The composites were investigated by high resolution transmission electronmicroscopy in order to investigate the morphology. The thermomechanical properties as storage, loss modulus, tan δ as well as the glass transition temperature (T g ) of the composites were estimated by dynamic mechanical thermal analysis (DMTA).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 625-627 
    ISSN: 1573-4846
    Keywords: composite materials ; sol-gel-process ; methacrylate copolymers ; dynamic-mechanical-analysis ; electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Sol gel derived composite materials were prepared from methacryloxypropyltrimethoxysilane (MPTS) and tetraethyleneoxidedimethacrylate (TEGDMA). The amount of MPTS in the composites was varied from 0 to 50 mole%. MPTS was prehydrolyzed at room temperature with 0,1 mole/l HCl/H2O. After complete removal of solvent calculated amounts of TEGDMA were added to the reaction mixture of the prehydrolyzed MPTS. Thermically initiated free radical copolymerization of the methacrylate endgroups was performed in the resulting mixture under nitrogen atmosphere using azobisisobutyronitril (AIBN) as initiator. The composites were investigated by high resolution transmission electronmicroscopy in order to investigate the morphology. The thermomechanical properties as storage, loss modulus, tan-as well as the glass transition temperature (T g ) of the composites were estimated by dynamic mechanical thermal analysis (DMTA).
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-07-13
    Description: Mrk 231, the nearest (z = 0.0422) quasar, hosts both a galactic-scale wind and a nuclear-scale iron low-ionization broad absorption line (FeLoBAL) outflow. We recently obtained a far-ultraviolet (FUV) spectrum of this object covering approx. 1150-1470A with the Cosmic Origins Spectrograph on board the Hubble Space Telescope. This spectrum is highly peculiar, highlighted by the presence of faint (〈 or approx.2% of predictions based on H(alpha)), broad (〉 or approx.10,000 km/s at the base), and highly blueshifted (centroid at approx. 3500 km/s) Ly(aplpha) emission. The FUV continuum emission is slightly declining at shorter wavelengths (consistent with F(sub lambda) Alpha Lambda(sup 1.7)) and does not show the presence of any obvious photospheric or wind stellar features. Surprisingly, the FUV spectrum also does not show any unambiguous broad absorption features. It thus appears to be dominated by the AGN, rather than hot stars, and virtually unfiltered by the dusty FeLoBAL screen. The observed Ly(alpha) emission is best explained if it is produced in the outflowing BAL cloud system, while the Balmer lines arise primarily from the standard broad emission line region seen through the dusty (Av approx. 7 mag) broad absorption line region. Two possible geometric models are discussed in the context of these new results.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN8650 , The Astrophysical Journal; 764; 1; 1-10
    Format: application/pdf
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