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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 34 (1995), S. 1545-1554 
    ISSN: 0570-0833
    Keywords: antiomony compounds ; bismuth compounds ; lead compounds ; thallium compounds ; tin compounds ; Antimony ; Bismuth ; Lead ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Alkali metal organometallic complexes (containing C-metal bonds) and the frequently structrually related alkali metal amides and alkoxides have been investigated extensively both in the solid state and in solution in the past two decades. However, until recently, the related complexes containing the heavier metallic and semi-metallic p block elements and the alkali and alkaline earth metals had rarely been studied in their own right. Recent solid-state structural studies have illustrated the immense structural diversity and bonding modes to be found within these species. One of the principal focuses of recent studies has been complexes containing organometallic anions of p block metals (e.g., triorganostannates, containing R3Sn-) in which metal-metal bonds occur between the heavy p block metal and the alkali or alkaline earth metal and the investigation of the nature of this bonding. The development of new synthetic routes has also allowed the preparation of a variety of anionic ligands with p block metal centers which promise new opportunities in coordination chemistry. In addition, the synthesis of a family of homologous anionic π complexes has given a fresh direction in the chemistry of p block metal metallocene complexes.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-07-04
    Description: Dawn's framing camera observed boulders on the surface of Vesta when the spacecraftwas in its lowest orbit (Low Altitude Mapping Orbit, LAMO). We identified, measured, and mapped boulders in LAMO images, which have a scale of 20 m per pixel. We estimate that our sample is virtually complete down to a boulder size of 4 pixels (80 m). The largest boulder is a 400 m‐sized block on the Marcia crater floor. Relatively few boulders reside in a large area of relatively low albedo, surmised to be the carbon‐rich ejecta of the Veneneia basin, either because boulders form less easily here or live shorter. By comparing the density of boulders around craters with a known age, we find that the maximum boulder lifetime is about 300 Ma. The boulder size‐frequency distribution (SFD) is generally assumed to follow a power law. We fit power laws to the Vesta SFD by means of the maximum likelihood method, but they do not fit well. Our analysis of power law exponents for boulders on other small Solar System bodies suggests that the derived exponent is primarily a function of boulder size range. The Weibull distribution mimics this behavior and fits the Vesta boulder SFD well. The Weibull distribution is often encountered in rock grinding experiments and may result from the fractal nature of cracks propagating in the rock interior. We propose that, in general, the SFD of particles (including boulders) on the surface of small bodies follows a Weibull distribution rather than a power law.
    Description: Key Points: We mapped boulders larger than 60 m on asteroid Vesta and found all associated with impact craters. The maximum lifetime of these large Vesta boulders is about 300 Ma, similar to that of meter‐sized lunar boulders. Their cumulative size‐frequency distribution is best fit by a Weibull distribution rather than a power law.
    Keywords: 523 ; Vesta ; Asteroid
    Type: article
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