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Photooxidation and Intramolecular Reaction of the Anthryl Moiety in [60]Fullerene Derivatives (2000)

Irngartinger, Hermann ; Weber, Anton ; Escher, Thomas

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 1647-1651

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ISSN: 1434-193X

Keywords: Fullerenes ; Anthracene ; Photooxidations ; Photochemistry ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---Anthracene groups have been linked to [60]fullerene by the [3+2] cycloaddition of the corresponding nitrile oxides or by esterification with a [60]fullerenol. The anthryl groups of the fullerene derivatives 3, 7, and 10 react readily with singlet oxygen to form the 9,10-epidioxides 4, 8, and 12 under photooxidation. The anthryl moiety of the fullerenol ester 10 also reacts with the fullerene skeleton to form the stable intramolecular Diels-Alder adduct 11.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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