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Mass spectrometric characterization of halo-sugar nucleosides (1986)

Alder, L. ; Donau, R. ; Stoesser, R. ; [et al.]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 13 (1986), S. 217-221

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ISSN: 1052-9306

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The fragmentations of 2′-, 3′- and 5′-halogenated deoxyribonucleosides were studied using low-resolution mass spectrometry and deuteration experiments. The major reaction pathways provide ions which allow detection of halogen introduction and simple differentiation between the 3′- and 5′-derivatives with respect to the 2′-derivatives. Additionally, it has been shown that the 2′-derivatives from 2,2′-anhydrouridine during the process of evaporation, thus affecting the spectra obtained.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bms.1200130503

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