ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The existence of two independent chromophores in [Ru(bipy)2(H2V)]+, where H2V- = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H2V)3]- analogue. In the former, the electronic band at 478 nm was assigned to the Ru → H2V MLCT transition, whereas the band at 415 nm was assigned to the Ru → bipy MLCT transition. In both species a tentative assignment is proposed for the enhanced modes based on comparison with related examples from the literature.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250231110
Permalink