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  • Analytical Chemistry and Spectroscopy  (1)
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    Electronic Resource
    Electronic Resource
    Massenspektrometrische Untersuchungen zu Dyotropen Umlagerungen (1976)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 11 (1976), S. 989-994 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The electron impact induced cleavage of the oxygen-carbon (or oxygen-silicon) bond is accompanied by an intramolecular migration of the silyl function onto the oxygen. Details of the mechanism formally correspond with a dyotropic rearrangement.
    Notes: Die elektronenstoßinduzierte spaltung der Sauerstoff-Kohlenstoff-(bzw. silicium)-Bindung wird durch eine gleichzeitige Wanderung der Silylfunktion zum Sauerstoff ermöglicht. Der mechanistische Verlauf entspricht teilweise dem von dyotropen Umlagerungen.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210110911
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