ISSN:
0030-4921
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
It has been shown by ESR spectroscopy that the title reaction involves abstraction of hydrogen from the phosphite, since at -10°C the reaction has a kinetic deuterium isotope effect, kH/kD, or ∼3. The rate constant for hydrogen abstraction is c. 2 × 104 M-1 s-1. There is no significant addition of alkoxyl radicals to the phosphite.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/mrc.1270071014
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