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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 10 (1987), S. 6-11 
    ISSN: 0935-6304
    Keywords: Capillary gas chromatography ; Negative ion mass spectrometry ; Plasma ; Estrone ; equilin ; Conjugated estrogens ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A procedure is described for the analysis of the estrogens equilin and estrone in human plasma following oral administration of conjugated estrogen preparations. After enzymatic hydrolysis of the sulfate conjugates, plasma proteins are precipitated with methanol and the estrogens extracted into ethyl acetate. Derivatization with the reagent flophemesylamine converts equilin and estrone into volatile pentafluorophenyldimethylsilyl ethers ideally suited to capillary gas chromatography-negative ion chemical ionization mass spectrometry. Using a 15 meter dimethyl silicone bonded phase fused silica capillary column separation of the estrone and equilin derivatives is achieved within 9 minutes. Selected ion monitoring of the intense negative molecular ions enables levels of 1 ng.ml-1 to be measured with coefficients of variation of 9.3 % and 14.2 % for estrone and equilin respectively. Plasma levels of the compounds are reported in two male volunteers up to 24 hours after dosing with 5 milligrams of Premarin™. (™ Ayerst Laboratories Inc., New York, USA.).
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 3-16 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We investigated the effect of concentration on the Brownian diffusion of uncharged rigid spheres. Monosize silica spheres were prepared according to the method of Stöber (1968). The particles were sterically stabilized by chemisorption of stearic alcohol at their surface by the method developed by van Helden (1981).Particle radius was 14.5 nm from electron micrographs of the coated particles. Osmotic pressure measurements of the sterically stabilized particles dispersed in cyclohexane showed that the particles behaved as hard spheres. The measurements agreed well with predictions from the Carnahan-Starling equation over the concentration range 0.0458 〈 φ 〈 0.37 where φ is the volume fraction of the particles in the suspension. Viscosity measurements of silica dispersions were made over the concentration range 0 〈 φ 〈 0.25. The relative viscosity over the range 0 〈 φ 〈 0.2 was fitted by ηr = 1 + 2.4φ + 7.1φ2. The coefficients 2.4 and 7.1 in this equation are in good agreement with the theoretical values of 2.5 and 6.2 obtained by Einstein(1906) and Batchelor(1977), respectively. The Brownian diffusion coefficient of the particles dispersed in cyclohexane was measured over the concentration range 0.0055 〈 φ 〈 0.248 using Taylor's hydrodynamic stability method. A laser fiber-optic system was used to measure the transient concentration profile along the capillary as indicated by a fluorescent dye. This technique offers the advantage of being direct and nonintrusive. The experimental diffusivity data were found to be well described by the generalized Stokes-Einstein equation(Batchelor, 1976) over the entire concentration range studied.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1555-1557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 790-795 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer coefficients have been measured over a range of Reynolds numbers for a solid-vapor mixture of parahydrogen discharging through a heated brass tube below the triple point pressure. A correlation is given which is shown by a formal analysis of a simple model to account for most of the system variables.
    Additional Material: 7 Ill.
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  • 5
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Peak nucleate boiling fluxes for liquid oxygen near 1 atm, have been measured on a 0.75-in.-diameter flat polished horizontal platinum surface located in a known, variable magnetic-field gradient that produced steady acceleration (which could be maintained indefinitely) on the oxygen acting in opposition to the earth's gravitation, gE. Measurements were made under condition ranging from net negative (directed away from the heated surface) accelerations of -0.03gE acting on the bulk liquid to the normal accelerations, 1.0gE. The results indicate that at zero g conditions for the bulk liquid, the peak nucleate boiling flux is ∼0.55 of the value at 1.0gE. For bulk-liquid accelerations ranging from ∼0.25 to 1gE, the experimental results confirm the ¼ power dependence of peak flux on acceleration as predicted by various correlations. However, below 0.25gE the peak flux becomes insensitive to the acceleration, varying approximately in proportion to the 1/14 power of the net acceleration. At bulk-liquid conditions of zero g (±0.005gE) the peak plux breaks sharply and falls by a factor of 10 between zero g and -0.03gE (for this apparatus).
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 890-897 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are presented for wall temperatures and heat transfer coefficients for solid-vapor mixtures of parahydrogen and nitrogen flowing in an electrically heated straight tube of length 40 times its diameter. These are interpreted by the application of flat plate, constant property boundary-layer theory to models in which the solid particle geometrical distribution takes on simple limiting forms. The observed enhancement of the heat transfer coefficient over that for gas alone traveling at the same velocity is qualitatively predicted as a function of a dimensionless heat flux, the Sterman parameter qw/ρvUλ.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 2059-2062 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 28 (1993), S. 635-642 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The potent endectocide 23-(O-methyloximino)-F28249α and related compounds were identified and characterized by mass spectrometry. The fragmentation pathway of 23-(O-methyloximino)-F28249α was identified by its high-resolution mass spectrum and the electron impact unit mass spectra of its homologs. This fragmentation pathway is presented and discussed.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 80 (1968), S. 631-631 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 50 (1961), S. 232-243 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wird über die Synthese von p-Hydroxybenzoylaceton, 4-Hydroxy-3-methylbenzoylaceton und 1-p-Hydroxyphenylpentandion-1,3 und über die Herstellung von gewissen Chelatpolyphenolen und den davon abgeleiteten Glycidyläthern berichtet. Die Härtung dieser Harze und die thermische Stabilität der ausgehärteten Produkte wurde untersucht. Analog aufgebaute chelierte aromatische Diamine wurden auch hergestellt und ihre Anwendung für das Aushärten von Epoxydharzen untersucht.
    Notes: The synthesis of p-hydroxybenzoylacetone, 4-hydroxy-3-methylbenzoylacetone and 1-p-hydroxyphenyl-1,3-pentandione is reported, together with the production of certain chelated polyphenols and the derived glycidyl ethers. The hardening of these resins and the thermal stability of the cured products and certain intermediates was studied. Analogously constituted chelated aromatic diamines have also been prepared and their use as hardeners for epoxy resin systems examined.
    Additional Material: 1 Tab.
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