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  • Analytical Chemistry and Spectroscopy  (8)
  • 13.60.Le Meson production  (1)
  • 1
    ISSN: 1434-601X
    Keywords: 12.38.Qk Experimental tests ; 13.40.-f Electromagnetic processes and properties ; 13.60.Le Meson production
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. An experiment on the radiative π{+}-meson photoproduction from the proton ( γp → γπ{+}n) was carried out at the Mainz Microtron MAMI in the kinematic region 537MeV 〈 Eγ 〈 817MeV, 140°≤ $ \theta_{{\gamma \gamma ^{\prime }}}^{{{{\rm cm}}}}$ ≤180°. The π{+}-meson polarizabilities have been determined from a comparison of the data with the predictions of two different theoretical models, the first one being based on an effective pole model with pseudoscalar coupling while the second one is based on diagrams describing both resonant and nonresonant contributions. The validity of the models has been verified by comparing the predictions with the present experimental data in the kinematic region where the pion polarizability contribution is negligible ( s1 〈 5mπ2) and where the difference between the predictions of the two models does not exceed 3%. In the region, where the pion polarizability contribution is substantial ( 5 〈 s1/mπ2 〈 15, -12 〈 t/mπ2 〈 - 2), the difference $\ensuremath{(\alpha -\beta )_{\pi^{+}}}$ of the electric (α) and the magnetic (β) polarizabilities has been determined. As a result we find $\ensuremath{(\alpha -\beta )_{\pi^{+}}=(11.6\pm 1.5_{{\rm stat}}\pm 3.0_{{\rm syst}}\pm 0.5_{{\rm mod}})\times 10^{-4}{}{\rm fm^{3}}}$ . This result is at variance with recent calculations in the framework of chiral perturbation theory.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 18 (1987), S. 323-326 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS spectra of the short-lived photoisomer of pinacyanol were obtained. From the CARS line frequencies, intensities, line shapes and depolarization ratios it can be concluded that a cis-isomer rather than a twisted configuration is observed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 25 (1994), S. 607-613 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Interferometric coherent anti-Stokes Raman scattering (ICARS) using incoherent laser light was used for time-resolved measurements of vibrational parameters of solutions of bis(dimethylamino)heptamethine iodide in the ground and the S1, state. The vibrations at 1124, 1195, 1285 and 1304 cm-1 have dephasing times in the range 0.3-1.1 ps. The shortest dephasing time is observed for the normal mode at 1195 cm-1 with a large amplitude for the N atoms. The coherence peak in the ICARS signal around zero delay is broadened due to coupling to the electronic transition. The same peak width of 80 fs is found using degenerate four-wave mixing.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 19 (1988), S. 517-522 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS measurements of the photoisomeriztion process of bisdimethylaminoheptamethine under different resonance and excitation conditions are presented and compared with model calculations. A Six-level model - a Rulliere-type model extended by one level - is suggested.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 183-189 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Model calculations of the absorption and the four quantities representing third-order non-linear susceptibility [the real and imaginary part of the excitation profile and of the resonance background component for resonance coherent anti-Stokes Raman scattering (CARS), R, J, b′ and b″, respectively] were carried out for polyatomic molecules. Comparison with previously acquired experimental data for bisdimethylaminoheptamethine perchlorate shows satisfactory agreement, except for b′ and b″. Some molecular parameters (the shift parameter of the active vibrations and the vibronic relaxation constant) were estimated. It is concluded that the resonance background is more sensitive to the model than the absorption and the excitation profile.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 21 (1990), S. 835-839 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A theoretical and experimental comparison of coherent anti-Stokes Raman scattering (CARS) and Raman-induced phase conjugation (RIPC) techniques has been carried out. In most cases the RIPC techniques are much more sensitive than CARS to deviations from the phase-matching conditions, from which it follows that for RIPC much higher accuracy of the alignment and optical homogeneity are necessary. In practice, only one RIPC variant with nearly copropagating pump waves and contrapropagating Stokes waves is applicable to obtain complete spectra. A CARS reflection technique is discussed for the investigation of highly absorbing samples.
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 19 (1988), S. 353-357 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS line-shape analysis has been applied to determine the parameters of the excited electronic state potential curves of a cyanine dye and its short-lived photoisomers during the process of photoisomerization. For this very complicated situation other methods for the estimation of these values would fail. The origin shift parameters determined are very small and the homogeneous line width is smaller than the line width of the absorption band.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman spectra of the three isoelectronic proton transfer systems 2-(2′-hydroxy-5′-methylphenyl)-benzotriazole (TIN), 2-(2′-hydroxyphenyl)benzothiazole (HBT) and 2-(2′-hydroxyphenyl)benzoxazole (HBO) were measured with excitation in the range of the S0-S1 absorption band of the enol tautomers. In each compound, about 15 modes in the wavenumber range between 120 and 1650 cm-1 show a strong coupling to the electronic transition. In TIN and HBT, combination tones of the strongest mode below 500 cm-1 and the vibrations at higher wavenumbers point to the strong anharmonicity of the low wavenumber motion. The experimental results are analysed by normal-mode calculations, which provide insight into the microscopic elongations in the molecules. The coupling strengths derived from the spectra are used to calculate the envelope of the S0-S1 absorption bands of TIN and HBT, reproducing the measured spectra very well. Theoretical simulations of the combination tone spectra give information on the vibrational modes involved in excited-state proton transfer.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 17 (1986), S. 425-430 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An extension of the Fleming and Johnson procedure is presented for determining the molecular third-order susceptibility parameters from three characteristic intensities within a CARS line profile (Imax, Imin, Imid). For CARS excitation close to a molecular one-photon resonance, these three intensity values taken from one spectrum do not suffice for the determination of all relevant parameters. A simple procedure is given for overcoming this by combining the information from all the spectra within a concentration series, keeping the frequency of the CARS pump laser fixed. Uncertainty in the measured Imid value is overcome by applying a least-squares fit of the spectra.Results obtained from resonance CARS measurements for Rhodamine 6G in ethanol are given.
    Additional Material: 4 Ill.
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