ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Sorting

Electronic Resource

Resolution effects of organic additives on the MEKC enantiomeric separations of tri aza aromatic ligand compounds of iron(II) (1995)

See, Marjorie M. ; Elshihabi, Said ; Burke, John A. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Journal of Microcolumn Separations 7 (1995), S. 199-206

add to mindlist on the mindlist

Details

ISSN: 1040-7685

Keywords: micellar electrokinetic chromatography ; capillary electrophoresis ; bile salts ; metal-ligands ; chiral separations ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: We have utilized micellar electrokinetic chromatography with sodium deoxycholate micelles to separate the enantiomers of bis(8-((pyridine-2-methylene)amino)quinoline)iron(II) hexafluorophosphate, Fe(PMAQ)2(PF6)2, bis(8-((pyridine-2-methylene)amino)lepidine iron(II) hexafluorophosphate, Fe(PMAL)2(PF6)2, and bis(1-(2-pyridinyl)ethylidine)-8-aminoquinoline iron(II) hexafluorophosphate, Fe(PEAQ)2(PF6)2. The influence of 13 water miscible organic additives on the resolution of each pair of enantiomers was investigated. Significant changes in resolution are seen depending upon the particular organic additive used in the separation buffer. In addition, the effects of acetone concentration on the resolution of these enantiomers in bile salt solution was investigated. Resolution for all three pairs of enantiomers is maximized in a buffer solution containing 15% acetone. © 1995 John Wiley & Sons, Inc.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mcs.1220070303

Permalink

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit