ISSN:
0009-2940
Keywords:
Silanolate
;
Aminosilanolate
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Lithium (dimethylamino)dimethylsilanolate (1) is obtained from trimeric dimethylsiloxane and lithium dimethylamide in quantitative yield. In the crystal 1 is a hexamer [LiOSiMe2(NMe2)]6 with crystallograpic C3i (S6, 3) symmetry. The molecule of 1 consists of a hexagonal prismatic (LiO)6 core and an N,O-chelating anion.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270912
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