ISSN:
0749-1581
Keywords:
Aluminum-27
;
Gallium-71
;
Aluminosilicates
;
Aluminophosphates
;
Aluminas
;
Gallosilicates
;
Gallophosphates
;
Gallias
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A linear relationship has been found to exist between the aluminum-27 and gallium-71 NMR chemical shifts of a series of structurally analogous aluminum and gallium compounds having only oxygen in the first metal coordination spheres; δ71Ga = 2.83(δ27Al) - 4.50. This relationship allows the prediction of 71Ga chemical shifts for such gallium compounds from the 27Al values already known for their aluminum analogues, and also a greater understanding of observed 71Ga chemical shifts.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260311002
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