ISSN:
1434-193X
Keywords:
Chromium
;
Aminocarbene complexes
;
Alkynes
;
C-H activation
;
Quinolizines
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
N-alkynyl aminocarbene complexes 15d and e derived from piperidin-2-one, 15f and g and from azepan-2-one yield, upon thermolysis, functionalized quinolizines 16-18d,e and homoquinolizines 16-18f,gas the result of a triple-bond insertion, a carbon-hydrogen bond activation, followed by a CO insertion. No reaction was observed in the case of complexes derived from pyrrolidin-2-one.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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