ISSN:
0009-2940
Keywords:
Bicyclo[3.2.0]hepta-1,3-dienyl complexes
;
Calculations, semiempirical
;
Alkyne trimerization
;
Cobalt complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Three isomeric bicyclo[3.2.0]heptadienes 1 - 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51-bicyclo[3.2.0]hepta-1,3-dienyl)(η41-cycloocta-1,5-diene)cobalt(I) (22), including an X-ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260323
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