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  • Aeolian dust  (1)
  • Biogeochemical cycles  (1)
  • 1
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2014
    Description: Marine particles include living and non-living solid components of seawater, representing a dynamic and chemically diverse mixture of phases. Through a combination of method development, basin-scale particulate collection and analyses, modeling, and field experiments, this thesis examines both the distributions of marine particulate trace metals and the underlying processes—inputs, scavenging, vertical and horizontal transport, and biotic uptake—in which marine particles participate. I first present the results of an intercalibration exercise among several US laboratories. We use inter-lab and intra-lab total elemental recoveries of these particles to determine our state of our intercalibration and to identify means of future improvement. We present a new chemical method for dissolution of polyethersulfone filters and compare it to other total particle digestion procedures. I then present the marine particulate distributions of the lithogenic elements Al, Fe, and Ti in the North Atlantic GEOTRACES section. A one-dimensional multi-box model that describes lithogenic particle distributions is also proposed and its parameter sensitivities and potential implications are discussed. I conclude with presentation of results from a series of bottle incubations in iron-limited waters using isotopically labeled Fe-minerals. We demonstrate solubilization of minerals ferrihydrite and fayalite via transfer of isotopic label into suspended particles.
    Description: Funding was provided by the Williams College Tyng Fellowship, the MIT/WHOI Academic Programs Office, the International and US GEOTRACES Offices, and U.S. National Science Foundation (NSF) #0960880 and #0963026 and PLR #0838921 to P.J. Lam.
    Keywords: Biogeochemical cycles ; Marine chemical ecology ; Melville (Ship) Cruise MV1101 ; Knorr (Ship : 1970-) Cruise KN199 ; Knorr (Ship : 1970-) Cruise KN204 ; Roger Revelle (Ship) Cruise RR1202
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part II: Topical Studies in Oceanography 116 (2015): 283-302, doi:10.1016/j.dsr2.2014.11.019.
    Description: In this paper, we present, describe, and model the first size-fractionated (0.8–51 µm; 〉51 µm) water-column particulate trace metal results from the US GEOTRACES North Atlantic Zonal Transect in situ pumping survey, with a focus on the lithogenic tracer elements Al, Fe and Ti. This examination of basin-wide, full-depth distributions of particulate elements elucidates many inputs and processes—some for bulk lithogenic material, others element-specific—which are presented via concentration distributions, elemental ratios, size-fractionation dynamics, and steady-state inventories. Key lithogenic inputs from African dust, North American boundary interactions, the Mediterranean outflow, hydrothermal systems, and benthic nepheloid layers are described. Using the refractory lithogenic tracer Ti, we develop a 1-D model for lithogenic particle distributions and test the sensitivities of size-fractionated open-ocean particulate Ti profiles to biotically driven aggregation, disaggregation rates, vertical sinking speeds, and dust input rates. We discuss applications of this lithogenic model to particle cycling in general, and to POC cycling specifically.
    Description: International and US GEOTRACES Offices (OCE-0850963 and OCE-1129603), and fellowship assistance from the Williams College Tyng Fellowship and MIT/WHOI Academic Programs Office to DCO.
    Keywords: Marine particles ; Lithogenic ; Particulate trace metals ; Aluminum ; Iron ; Titanium ; GEOTRACES ; Aeolian dust ; Aggregation ; Disaggregation ; Sinking speed ; Scavenging
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Format: application/msword
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