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  • Surface physics, nanoscale physics, low-dimensional systems  (7)
  • Chemistry  (6)
  • Adsorption from solutions  (4)
  • 1
    Publication Date: 2015-03-26
    Description: Author(s): Rico Friedrich, Vasile Caciuc, Nikolai S. Kiselev, Nicolae Atodiresei, and Stefan Blügel We theoretically explore through systematic multiscale ab initio and Monte Carlo calculations how the surface magnetism of a ferromagnetic surface can be fine-tuned by nonmagnetic organic molecules containing a single π bond. We demonstrate that a magnetic hardening or softening can be induced depen... [Phys. Rev. B 91, 115432] Published Wed Mar 25, 2015
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 2
    Publication Date: 2018-10-30
    Description: Author(s): D. B. Karki and Mikhail N. Kiselev We developed a theoretical framework which extends the method of full counting statistics (FCS) from conventional single-channel Kondo screening schemes to a multichannel Kondo paradigm. The developed idea of FCS has been demonstrated considering an example of a two-stage Kondo (2SK) model. We analy... [Phys. Rev. B 98, 165443] Published Mon Oct 29, 2018
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 3
    Publication Date: 2017-09-12
    Description: Author(s): D. B. Karki and Mikhail N. Kiselev We investigate thermoelectric transport through a SU ( N ) quantum impurity in the Kondo regime. The strong-coupling fixed-point theory is described by the local Fermi-liquid paradigm. Using Keldysh technique we analyze the electric current through the quantum impurity at both finite bias voltage and f... [Phys. Rev. B 96, 121403(R)] Published Mon Sep 11, 2017
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 4
    Publication Date: 2018-05-03
    Description: Author(s): D. B. Karki, Christophe Mora, Jan von Delft, and Mikhail N. Kiselev A multiorbital quantum impurity with effective spin S〉1/2 connected to several reservoirs of conduction electrons can lead to a Kondo effect, exhibiting multistage screening. The ground state of a prototypical nanoscale device consisting of an S=1 quantum impurity connected to two conducting reservoirs is a spin singlet, formed via a two-stage Kondo screening mechanism. Understanding the equilibrium and nonequilibrium properties of the strong-coupling regime resulting from this two-stage screening has been an open problem for many years. Here, the authors offer a detailed description in terms of an effective local two-color Fermi liquid theory. [Phys. Rev. B 97, 195403] Published Wed May 02, 2018
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 5
    Publication Date: 2017-12-02
    Description: Author(s): Arjan J. A. Beukman, Folkert K. de Vries, Jasper van Veen, Rafal Skolasinski, Michael Wimmer, Fanming Qu, David T. de Vries, Binh-Minh Nguyen, Wei Yi, Andrey A. Kiselev, Marko Sokolich, Michael J. Manfra, Fabrizio Nichele, Charles M. Marcus, and Leo P. Kouwenhoven The spin-orbit interaction is investigated in a dual gated InAs/GaSb quantum well. Using an electric field, the quantum well can be tuned between a single-carrier regime with exclusively electrons as carriers and a two-carrier regime where electrons and holes coexist. The spin-orbit interaction in b... [Phys. Rev. B 96, 241401(R)] Published Fri Dec 01, 2017
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
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  • 6
    Publication Date: 2018-02-06
    Description: Author(s): T. K. T. Nguyen and M. N. Kiselev We propose a model describing Seebeck effect on a weak link between two quantum systems with fine-tunable ground states of Fermi and non-Fermi liquid origin. The experimental realization of the model can be achieved by utilizing the quantum devices operating in the integer quantum Hall regime [Z. If... [Phys. Rev. B 97, 085403] Published Mon Feb 05, 2018
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 7
    Publication Date: 2018-01-13
    Description: Author(s): A. V. Parafilo and M. N. Kiselev We propose a realization of mechanically tunable Ruderman-Kittel-Kasuya-Yosida interaction in a double quantum dot nanoelectromechanical device. The coupling between spins of two quantum dots suspended above a metallic plate is mediated by conduction electrons. We show that the spin-mechanical inter... [Phys. Rev. B 97, 035418] Published Fri Jan 12, 2018
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 17 (1983), S. 143-148 
    ISSN: 1612-1112
    Keywords: Liquid chromatography ; Intermolecular interactions ; Adsorption from solutions ; Chemically modified layers in LC ; Conformation of bonded chains
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary For the investigation of intermolecular interactions in adsorption from solution, which are the basis of selectivity in molecular liquid chromatography (LC), it is convenient to use the LC method itself. Using this method the Henry's constants, K1, and other thermodynamic adsorption characteristics of hydrocarbons and of a series of polar substances on hydroxylated silica surface were determined from aqueous solutions. On the basis of the adsorption of hydrocarbons from water solutions the structure of the chemically modifying layers formed by different hydrocarbon groups on the silica surface is considered. The role of conformation ability of straight-chain bonded phases is demonstrated. Hydrocarbons are adsorbed on the hydroxylated silica surface more strongly from aqueous solutions than from solutions in saturated hydrocarbons and their retention increases with the increase in the number of carbon atoms in the molecule. The retention in LC is determined by the intermolecular interaction of the solute and solvent molecules with the adsorbent, as well by the contribution of the intermolecular interaction, between the solute and the solvent. The thermodynamic characteristics of adsorption of cymarin from water-ethanol solutions on hydroxylated silica gel and on silica gel surface modified by diphenylsilyl groups is compared. The solubility of silica gel modified by diphenylsilyl groups at different composition of water-ethanol eluent at different temperatures is investigated.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 20 (1985), S. 525-528 
    ISSN: 1612-1112
    Keywords: Liquid-solid chromatography ; Frontal analysis ; Adsorption isotherms ; Adsorption from solutions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The automatic frontal chromatography installation was described. By this chromatographic method the adsorption isotherm of benzene from n-heptane solutions on hydroxylated surface of silica with various porosity has been determined. This investigation was performed at different flow rates of eluent and in a wide range of concentrations. The isotherm of adsorption obtained by this chromatographic method has been compared with the results of the static measurements. The coincidence of adsorption isotherms measured at the various flow rates are shown to be a criterion of proximity the chromatographic process to the equilibrium.
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  • 10
    ISSN: 1612-1112
    Keywords: Adsorption from solutions ; Liquid chromatography ; Cardiac glycosides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Using the cardiac glycoside cymarin as the example the application of liquid chromatography for the study of adsorption from solutions and the determination of the corresponding thermodynamic characteristics was investigated. The adsorption isotherm of cymarin at small concentrations from a water-ethanol solvent on silica gel modified by dimethyldichlorosilane was measured under static conditions using analytical LC to determine the concentrations of solutions after adsorption. The values of the Henry constants were obtained by extrapolating the slope of the adsorption isotherm down to zero concentration. The specific retention volumes for different but small sample sizes of cymarin in the chromatographic column were measured, the adsorbent and the water-ethanol eluent being the same as in the static conditions. The specific retention volume for a small (zero) sample size determined by liquid chromatography experiment coincides with the Henry constant of cymarin adsorption determined in static conditions. In favourable cases liquid chromatography can be used to determine the equilibrium constants for adsorption from solution. The dependence of the Henry constants on temperature was investigated for several cardiac glycosides. The influence of the modification of the adsorbent surface on the separation of the cardiac glycosides was also studied.
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