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  • 1
    ISSN: 1434-4475
    Keywords: Adsorbent heterogeneity ; Adsorption at the liquid-solid interface ; Adsorption from multicomponent solutions ; Thermodynamic functions of adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Konkurrenzadsorption von Multikomponenten-Mischungen von Nichtelektrolyten an energetisch heterogenen Festkörpern wird im Rahmen der Statistischen Thermodynamik beschrieben. Die Integralgleichungen für fundamentale thermodynamische Größen, die Konkurrenzadsorption an der Festkörper — Flüssigkeit Phasengrenze charakterisieren, sind ausgeführt. Es wurden extensive Modelluntersuchungen zur Illustration des Einflußes der Heterogenität der Adsorbenten auf das Verhalten dieser thermodynamischen Größen durchgeführt.
    Notes: Summary A simple model for competitive adsorption from multicomponent non-electrolytic liquid mixtures on energetically heterogeneous solid surfaces is discussed in terms of statistical thermodynamics. Integral equations are derived for the fundamental thermodynamic quantities that characterize competitive adsorption at the liquid-solid interface. Extensive model studies are presented in order to illustrate the influence of adsorbent heterogeneity on the behaviour of these thermodynamic quantities.
    Type of Medium: Electronic Resource
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