ISSN:
1434-4475
Keywords:
Chiral recognition
;
Chiral discrimination
;
Smectite
;
Clay minerals
;
Surface charge
;
Intercalation
;
Adsorption capacities
;
Diffraction patterns
;
Trisdiimine complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Adsorptionisotherms of tris-(3,3′-bi-1,2,4-triazine)iron(II) complexes onto a well characterized montmorillonite are discussed in respect to the relative charge densities of adsorbent and adsorbat. While the adsorption capacities for trisbipyridyl and trisphenanthroline complexes differ for the racemates and the enantiomers they are equal for these complexes. Adsorption is limited to a monolayer. This backs the proposal that the observed chiral recognition phenomena are founded solely in the lateral interactions between adsorbats.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00818162
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