ISSN:
0170-2041
Keywords:
Fatty acid
;
Oleic acid
;
Stearic acid, 17- and 18-substituted
;
Acetylene zipper
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Stearolic acid (2) was prepared from oleic acid (1) and converted to 4, 5, and 7 by way of the „acetylene zipper“ reaction. Compounds 5 and 7 were transformed to the (ω - 1) ketones 8 and 9 and dimerized by way of the Glaser coupling reaction to 11 and 12. At daylight, 12 polymerizes to a blue polymer.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1991199101178
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